应用化学 ›› 2015, Vol. 32 ›› Issue (1): 19-26.DOI: 10.11944/j.issn.1000-0518.2015.01.140078

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磁性纳米粒子负载钯催化剂在C—C键偶联反应中的应用

冯翠兰a*, *, 刘建平a, b, 桂建舟b, 刘澜涛a*, *   

  1. a商丘师范学院 化学化工学院 河南 商丘 476000; 
    b辽宁石油化工大学 化学与材料科学学院 辽宁 抚顺 113000
  • 收稿日期:2014-03-14 修回日期:2014-05-19 出版日期:2015-01-06 发布日期:2015-01-06
  • 通讯作者: 通讯联系人:冯翠兰,副教授; Tel/Fax:0370-2595072; E-mail:fengcuilanfan@163.com; 研究方向:绿色不对称催化
  • 基金资助:
    国家自然科学基金(21102087)资助项目; 河南省科技厅科技攻关项目(112102210477); 河南省高等学校青年骨干教师资助计划(2011GGJS-157)

Application of Magnetic Nanoparticles Supported Pd Catalysts in C—C Bond Formation Reactions

FENG Cuilana, *, LIU Jianpinga, b, GUI Jianzhoub, LIU Lantaoa, *   

  1. aChemistry & Chemical Engineering,Shangqiu Normal University,Shangqiu,He'nan 476000,China; 
    bSchool of Chemistry and Material Science,Liaoning Shihua University,Fushun,Liaoning 113000,China
  • Received:2014-03-14 Revised:2014-05-19 Published:2015-01-06 Online:2015-01-06
  • Contact: Corresponding author:FENG Cuilan, associate professor; Tel/Fax:0370-2595072; E-mail:fengcuilanfan@163.com; Research interests:green organocatalytic reaction
  • Supported by:

    Supported by the National Natural Science Foundation of China(No.21102087), Key Technologies R & D Program of He'nan Scientific and Technological Committee(No.112102210477), Funding Scheme for Young Teachers in Colleges and Universities in He'nan Province(No.2011GGJS-157)

摘要:

磁性纳米粒子(MNPs)负载钯催化剂因具有高的催化活性及易于原位磁分离回收等优点而得到快速发展,成为一类具有广泛应用前景的纳米催化剂,在学术及工业领域均受到广泛的关注。 本文对近年来MNPs负载钯催化剂在Suzuki、Heck等C—C偶联反应中的应用研究进行简要阐述,并对其发展前景进行了展望。

 

关键词: 磁性纳米粒子, 负载钯催化剂, C-C键偶联反应, Suzuki偶联反应, Heck偶联反应

Abstract:

Due to their high catalytic activity and easily recoverable characters, the magnetic nanoparitcles(MNPs) supported catalysts have received extensive attention in academy as well as industry. Thus, they have been developed into a kind of sustainable nanocatalysts with wide application prospect. In this paper, the recent development in the synthesis and application of MNPs supported palladium catalysts for a variety of C—C coupling reactions such as Suzuki coupling reactions, Heck coupling reactions, etc., is reviewed. A brief outlook of their developments is also presented.

Key words: magnetic nanoparticles, supported Pd catalysts, C-C coupling reaction, Suzuki coupling reaction, Heck coupling reaction

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