中华医学超声杂志

应用化学 ›› 1996, Vol. 0 ›› Issue (5): 10-13.

• 研究论文 • 上一篇    下一篇

以硝基、氨基修饰改性聚苯醚

潘雁, 黄玉惠, 丛广民   

  1. 中国科学院广州化学研究所 广州 510650
  • 收稿日期:1995-11-22 修回日期:1996-03-18 出版日期:1996-10-10 发布日期:1996-10-10
  • 基金资助:
    国家自然科学基金;国家科委国家基础性研究重大关键项目

Modification of Poly(2,6-dimethyl-1,4-phenylene Oxide) with Nitro or Amino Functional Groups

Pan Yan, Huang Yuhui, Cong Guangmin   

  1. Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650
  • Received:1995-11-22 Revised:1996-03-18 Published:1996-10-10 Online:1996-10-10

PDF

395

摘要： 将聚苯醚硝化、还原,分别合成了硝化聚苯醚和胺化聚苯醚,最高硝基、氨基取代度分别为95%、65%.讨论了各种反应条件对取代度的影响,并对修饰改性的聚苯醚进行了表征。

关键词: 聚苯醚, 胺化, 硝化, 取代度

Abstract: The chemical modification of poly(2,6-dimethyl-1,4-phenylene oxide)(PPO) has been carried out by incorporating nitro or amino groups in the PPO backbone. The obtained maximum monosubstitution value is 95% or 65% respectively. The effects of reaction conditions on the functional group contents in PPO were discussed. The modified PPO obtained was characterized by FT-IR、1H NMR spectroscopy, nitrogen analysis, solubility test and X-ray diffraction study.

Key words: poly(phenylene oxide), amination, nitration, substitution value

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