中华医学超声杂志

应用化学 ›› 1994, Vol. 0 ›› Issue (1): 20-23.

• 研究论文 • 上一篇    下一篇

稀土饱和漆酚冠醚配合物的合成及镧(Ⅲ)离子选择电极的研究

潘恩霆1, 周雪梅1, 黄载福2   

  1. 1. 广西师范大学化学系 桂林 541004;
    2. 武汉大学环境科学系 武汉
  • 收稿日期:1992-12-31 修回日期:1993-10-12 出版日期:1994-02-10 发布日期:1994-02-10

Syntbcsis of saturatd Urushiol Crown Ether Rare EarthComplexes andthe Lanthanum(Ⅲ)Ion Selective Electrode Using the Same

Pan Enting1, Zhou Xuemei1, Huang Zaifu2   

  1. 1. Department of Chemistry, Guaiigxi Normal University, Guilin 541004;
    2. Departmeiit of Environmental Science, Wuhan University, Wuhan
  • Received:1992-12-31 Revised:1993-10-12 Published:1994-02-10 Online:1994-02-10

PDF

455

被引次数

11

摘要： 报道了饱和漆酚30-冠-10轻稀土(Ln=La～Nd)配合物的合成,通过元素分析、IR、UV、摩尔电导和DTA等方法对配合物进行了表征;并以饱和漆酚冠醚为传感活性物质,研制了镧(Ⅲ)离子选择电极,它的线性响应范围为1×10-2～1×10-6mol/L La(NO3)3,检测下限为1×10-6mol/L La(NO3)3,对镧离子的选择优于其他镧离子电极。

关键词: 饱和漆酚, 冠醚, 稀土配合物, 离子选择电极

Abstract: The complexes of rare earth (Ln = La～Nd)with saturated urushiol crown ether (DSU30C10) have been synthesized in acetonitrile solution. The complexes have been characterized by elemental analysis, IR and UV spectra, molar conductance and differential thermal analysis,The lanthanutn iOn selective electrode with saturated urushiol crown ether as a neutral carrier exhibited linear responses in 1×10-2～1×10-6mol/L La(NO3)3. The electrode showed better selectivity than other La(Ⅲ)electrodes reported in literature。

Key words: urushiol, crown ether, rare earth complex, ion selective electrode

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