应用化学 ›› 1993, Vol. 0 ›› Issue (5): 22-27.

• 综合评述 • 上一篇    下一篇

两性树脂与水处理

徐和德, 李国明, 陈文森   

  1. 华南师范大学化学系 510631 广州
  • 收稿日期:1993-04-01 修回日期:1993-06-02 出版日期:1993-10-10 发布日期:1993-10-10
  • 基金资助:
    国家自然科学基金资助项目

AMPHOTERIC ION EXCHANGE RESINS FOR WATER TREATMENT

Xu Hede, Li Guoming, Chen Wensen   

  1. Department of Chemistry, South China Normal University, 510631 Guangzhou
  • Received:1993-04-01 Revised:1993-06-02 Published:1993-10-10 Online:1993-10-10

摘要: 两性树脂可简单地分为两大类:一类是不能形成内盐的,其性能与阴和阳离子交换树脂的混合物相近。另一类则能形成内盐,并由此产生了一系列新的特性,这类树脂的选择性,膨胀性及吸附容量等在一定范围内都随溶液中电解质浓度提高而提高,因此可适用于浓电解质溶液的分离提纯。本文重点论述了形成内盐的一些规律性,尤其是树脂的交联度和功能基性质以及环境条件如温度、浓度和pH等与形成内盐的关系。

关键词: 两性树脂, 蛇笼树脂, 内盐键, 脱盐, 水处理

Abstract: Amphoteric ion exchange resins(AIER) may be divided into two kinds:First one can not form inner salt and there is no interaction between anionogen and cationogen in it, its property is similar to that of the mixture of anion and cation exchange resins. The second kind can form inner salt,from which a series of new properties ate produced. The selectivity, swelling and absorption capacity of the second kind of AIER all are increased with the concentration of the electrolyte solution in a definite concentration range. The second kind of AIER is useful for separation and purification of concentrated electrolyte solution. This review puts emphasis on the formation of inner salt, especially on the effect of crosslinking and ionogen on it.

Key words: amphoteric resin, snake-cage resin, inner salt, desalination, water treatment