应用化学 ›› 1991, Vol. 0 ›› Issue (3): 89-92.

• 研究简报 • 上一篇    下一篇

均匀铁氧化物(含水)胶体粒子的制备

张凯华, 姜继森, 陈龙武   

  1. 华东师范大学化学系, 上海 200062
  • 收稿日期:1990-05-10 修回日期:1990-08-25 出版日期:1991-06-10 发布日期:1991-06-10
  • 基金资助:
    国家自然科学基金

PREPARATION OF UNIFORM FERRIC HYDROUS OXIDE PARTICLES

Zhang Kaihua, Jiang Jisen, Chen Longwu   

  1. Department of Chemistry, East China Normal University, Shanghai 200062
  • Received:1990-05-10 Revised:1990-08-25 Published:1991-06-10 Online:1991-06-10

摘要: 均匀胶体具有广阔的应用前景[1],开展这种胶体的研究具有重要的理论和实际意义。铁氧化物(含水)均匀胶体粒子首先在Matijevi'c的实验室制得[2]。不久前,我们在无防尘设备的一般实验室条件下成功地制得了二种直径为0.090μm的球状α-Fe2O3胶体粒子[3],并开展了均匀胶体的性质研究[4,5]。为了进一步开展均匀胶体特性及其表面性质的研究,就要制取不同大小和不同形状的胶体粒子,并掌握其制备规律。本文旨在探讨制备铁氧化物胶体粒子对反应液铁离子的浓度、盐酸量以及陈化时间等因素对粒子物相、形状等的影响。

关键词: α-Fe2O3, β-FeOOH, FeCl3, 均匀粒子, 制备

Abstract: The uniform particles of α-Fe2O3 with diameters of 0.050~0.80μm were prepared underfollowing conditions 0.010~0.050mol/L of FeCl3, 0.0010mol/L HCl and 168h of aging at 105±1℃.The particles can be made in the shape of a cube or sphere.With a reducedaging time (24h), spherical particles were only obtained from the solution of FeCl3(0.018mol/L).The mean diameter of the particles was about 0.09μm.Rodlike β-FeOOH were formed under heating a solution of FeCl3(0.100~0.320mol/L) with HCl (0.0010mol/L).

Key words: FeCl3, α-Fe2O3, β-FeOOH, uniform particle, preparation