应用化学 ›› 1991, Vol. 0 ›› Issue (2): 78-81.

• 研究简报 • 上一篇    下一篇

COPU/PMMA AB交联聚合物的性能

杜郢, 刘文忠, 韩孝族   

  1. 中国科学院长春应用化学研究所, 长春 130022
  • 收稿日期:1989-12-29 修回日期:1990-05-28 出版日期:1991-04-10 发布日期:1991-04-10
  • 基金资助:
    国家自然科学基金

PROPERTIES OF COPU/PMMA AB CROSSLINKED POLYMERS

Du Ying, Liu Wenzhong, Han Xiaozu   

  1. Changchun Institute of Applied Chemistry, Academia Sintca, Changchun 130022
  • Received:1989-12-29 Revised:1990-05-28 Published:1991-04-10 Online:1991-04-10

摘要: AB交联聚合物(ABCP)[1]是由聚合物A链与化学组成不同的聚合物B链交联构成。它的网络结构不同于IPN。IPN是由两个独立的网络构成,而在ABCP中仅存在一个聚合物网络。目前人们对它远不及对IPN了解得多。 本文选用蓖麻油为原料,与甲基丙烯酸甲酯共聚,合成了一种ABCP。研究了它的力学性能,转变与松弛,相容性及形态结构与组成及交联密度的关系。

关键词: AB交联聚合物, 蓖麻油, MMA, 甲苯二异氰酸酯, 力学性能

Abstract: The effects of composition, crosslink density of COPU/PMMA AB crosslinked polymerson their mechanical, dynamic mechanical properties, compatibility an d morphology werestudied.The results show that increasing the content of hard segment and decreasing cros-slink density make the compatibility of the polymer worse.TEM shows that the COPU/PMMA AB crosslinked polymer systems transform from apparent compatible to semi-compatibleone with the increase of hard segment content,and the phase inversion occurs when PMMA content reaches to 50%.The damping value is controlled mainly by the crosslink density,whereas the Tg value by the component.

Key words: AB crosslinked polymer, castor oil, MMA, toluene disocyanate, mechanical property