应用化学 ›› 2011, Vol. 28 ›› Issue (10): 1184-1188.DOI: 10.3724/SP.J.1095.2011.00677

• 研究论文 • 上一篇    下一篇

琥珀酸酯磺酸盐Gemini表面活性剂的合成及表面活性

贾金英,闫杰,安悦*,崔冬梅,杨陈希,陈晓峰,王拓,佟妍   

  1. (辽宁师范大学化学化工学院 大连 116029)
  • 收稿日期:2010-11-16 修回日期:2011-01-07 出版日期:2011-10-10 发布日期:2011-10-10
  • 通讯作者: 安悦,教授; Tel:0411-84258991; E-mail:anyue_11@163.com; 研究方向:有机合成
  • 基金资助:
    辽宁省教育厅资助项目(2008349)

Synthesis and Surface Activities of Gemini Sodium Sulfosuccinate

JIA Jinying, YAN Jie, AN Yue*, CUI Dongmei, YANG Chenxi, CHEN Xiaofeng, WANG Tuo, TONG Yan   

  1. (School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029)
  • Received:2010-11-16 Revised:2011-01-07 Published:2011-10-10 Online:2011-10-10
  • Contact: Anyue

摘要:

以1-十二醇、1-十四醇、1-十六醇、1-十八醇、马来酸酐和乙二醇为主要原料,合成4种琥珀酸酯磺酸盐Gemini表面活性剂;借助红外光谱和核磁共振氢谱对所合成的化合物结构进行了表征。 4种表面活性剂均具有较低的临界胶束浓度,较强的乳化性能以及较好的泡沫性能。 进一步讨论了4种表面活性剂结构与性能的关系。

关键词: Gemini 表面活性剂, 临界胶束浓度, 表面张力, 乳化性能, 泡沫性能

Abstract:

Four different sodium sulfosuccinates were synthesized using 1-dodecanol, 1-tetradecanol, 1-hexadecanol, 1-octadecanol, maleic anhydride and ethylene glycol as starting materials. The structures of the target compounds were identified by IR and 1H NMR. The results of surface tensions, foaming abilities and emulsifiability measuring show that every compound has lower critical micelle concentration(cmc), stronger emulsifying and better foaming ability. In addition, the structures and the performance relations of the four compounds were discussed.

Key words: sodium sulfosuccinate, Gemini surfactant, cmc, surfactivity

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