基于MX4结构的配位化合物析氢反应催化性能

doi:10.11944/j.issn.1000-0518.2018.03.170453

摘要/Abstract

摘要：

具有MX₄结构的(M=Fe,Co,Ni,Cu等,X=N,S,Se等)小分子配位化合物及配位聚合物(MX₄催化剂),由于其新颖的结构和优异的电催化析氢性能受到研究人员越来越多的关注。本文综述了MX₄催化剂的研究进展,其中MX₄催化剂活性受金属中心、配位原子、配体的结构以及材料的形貌、尺寸等因素的影响。理论计算有助于分析催化剂中这些因素对催化剂活性的影响,也有助于通过理论模拟,设计更合理的催化剂分子结构。

关键词: 催化析氢反应, 配位化合物, MX₄结构

Abstract:

The coordination complexes based on MX₄(M=Fe,Co,Ni,Cu, et al, X=N,S,Se, et al.) structure have attracted a lot of attentions due to their novel structure and good electrocatalytic performance in hydrogen evolution reaction(HER). This review shows the recent research progresses of their catalytic properties for HER. The HER activities of MX₄ catalysts are affected by many factors, such as the metal center, coordination atoms, the ligand, the morphology and size of catalysts. Theoretical calculations are very helpful for understanding their influences on the activities of the catalysts and can further help us design more catalysts with higher activities.

Key words: catalytic hydrogen evolution reaction, coordination complex, MX₄ structure

姚会影, 杨涛, 黄幸, 朱嘉, 李青, 徐伟, 迟力峰. 基于MX₄结构的配位化合物析氢反应催化性能[J]. 应用化学, 2018, 35(3): 328-341.

YAO Huiying, YANG Tao, HUANG Xing, ZHU Jia, LI Qing, XU Wei, CHI Lifeng. Coordination Complexes Based on MX₄ Structure as Catalyst for Hydrogen Evolution Reaction[J]. Chinese Journal of Applied Chemistry, 2018, 35(3): 328-341.

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基于MX₄结构的配位化合物析氢反应催化性能

Coordination Complexes Based on MX₄ Structure as Catalyst for Hydrogen Evolution Reaction

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