应用化学 ›› 2015, Vol. 32 ›› Issue (4): 428-432.DOI: 10.11944/j.issn.1000-0518.2015.04.140298

• 研究论文 • 上一篇    下一篇

炭负载Pd/Ce双金属催化剂对Heck反应的催化性能

徐启杰, 时文中*, 左春山, 刘大勇, 杨春, 赵翔, 刘鹏程   

  1. 黄淮学院化学化工系 河南 驻马店 463000
  • 收稿日期:2014-08-27 修回日期:2014-11-20 出版日期:2015-04-10 发布日期:2015-04-10
  • 通讯作者: 通讯联系人:时文中,教授;Tel/Fax:0396-28531; Email:shiwz64@163.com; 研究方向:稀土化合物的制备及性能
  • 基金资助:
    河南省自然科学基金项目(062427004, 092300410121,112300410184)

Catalytic Properties of Carbon Supported Pd/Ce Bimetallic Catalyst on Heck Reaction

XU Qijie, SHI Wenzhong*, ZUO Chunshan, LIU Dayong, YANG Chun, ZHAO Xiang, LIU Pengcheng   

  1. Department of Chemistry & Chemical Engineering,Huanghuai University,Zhumadian,He'nan 463000,China
  • Received:2014-08-27 Revised:2014-11-20 Published:2015-04-10 Online:2015-04-10
  • Contact: Corresponding author:SHIWenzhong, professor; Tel/Fax:0396-2853156; E-mail:shiwz64@163.com; Research interests: preparation and properties of rare earth compounds
  • Supported by:

    Supported by He’nan Province Natural Science Fund project (No.0624270040, No.092300410121, No.112300410184)

摘要:

通过简便的方法制备了炭负载Pd/Ce双金属催化剂,利用Pd/Ce双金属催化剂的协同效应提高催化剂对Heck反应的催化效率。 以碘苯与丙烯酸的Heck芳基化反应为模型反应,研究了反应条件对催化剂催化性能的影响。 结果显示,在反应温度为130 ℃,反应时间为5 h,N,N-二甲基甲酰胺(DMF)作为溶剂和三丁胺(Bu3N)作为碱的条件下,炭负载Pd/Ce双金属催化剂对丙烯酸和碘苯的Heck芳基化反应具有良好的催化性能,产率达到70%以上。 另外,该催化剂属于非均相催化剂,催化剂易与反应溶液分离;也可以重复利用,使用3次反应产率仍达到66.9%,显示了炭负载Pd/Ce双金属催化剂良好的催化活性。

 

关键词: Heck反应, 双金属催化剂, 催化效率

Abstract:

Carbon supported Pd/Ce bimetallic catalyst was prepared readily for Heck reaction. The effect of reaction conditions on the catalytic properties of carbon supported Pd/Ce bimetallic catalyst was studied in details with the model Heck reaction of iodobenzene and acrylic acid. The results show that carbon supported Pd/Ce bimetallic catalyst can effectively catalyze the Heck reactions under the conditions of 130 ℃, 5 h, DMF as the solvent, and Bu3N as the base to afford the product with a yield of over 70%. Additionally, the heterogeneous carbon supported Pd/Ce bimetallic catalyst can be easily separated from the reaction solution. Furthermore, the catalyst can be reused for 3 times with a yield of 69% and without the significant loss of catalytic efficiency.

Key words: Heck reaction, bimetallic catalyst, catalytic

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