中华医学超声杂志

应用化学 ›› 1998, Vol. 0 ›› Issue (1): 22-24.

• 研究论文 • 上一篇    下一篇

2,2,4,4-四对羟甲基酚氧基-6,6-二苯基三聚磷腈的合成

胡源1, 邵宗龙2, 董华1, 余亚平2, 毛羽华2, 范维澄1   

  1. 1. 中国科学技术大学火灾科学国家重点实验室 合肥 230026;
    2. 安徽大学化学系
  • 收稿日期:1997-05-04 修回日期:1997-09-15 出版日期:1998-02-10 发布日期:1998-02-10
  • 基金资助:
    国家自然科学基金

Synthesis of 2, 2, 4, 4-Tetra(4′-hydroxymethylphenoxy)-6, 6-diphenylcyclotriphosphazene

Hu Yuan1, Shao Zonglong2, Dong Hua1, Yu Yaping2, Mao Yuhua2, Fan Weicheng1   

  1. 1. State Key Laboratory of Conflagration Science, China University of Science and Technology, Hefei 230026;
    2. Department of Chemistry, Anhui University
  • Received:1997-05-04 Revised:1997-09-15 Published:1998-02-10 Online:1998-02-10

PDF

389

被引次数

4

摘要： 通过Friedel-Crafts反应,将本基引入到六氯环三磷腈上,然后由亲核取代反应和氢化还原反应,合成了2,2,4,4-四对羟甲基酚氧基-6,6-二苯基三聚磷腈,探索了各步的合成、分离方法,并对化合物的结构进行了表征.

关键词: 磷腈化合物, 四对羟甲基酚氧基二苯基三聚磷腈, 亲核取代, 氢化还原

Abstract: Phenyl was introduced into hexachlorocyclotriphosphazene by Friedel-Crafts reac-tion and the title compound was synthesized by nucleophilic substitution and hydrogenationreaction.Its structure was characterized by elemental anlaysis, IR, NMR and MS measure-ments.

Key words: phosphazene, tetra (hydroxymethylphenoxy)diphenyl-cyclotriphosphazene, nucle-ophilic substitution, hydrogenation

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