应用化学 ›› 1996, Vol. 0 ›› Issue (2): 33-36.

• 研究论文 • 上一篇    下一篇

pH和电解质对氢氧化铝镁溶胶稳定性的影响

侯万国, 于耀芹, 张春光, 吴连勇, 王果庭   

  1. 山东大学胶体与界面化学研究所 济南 250100
  • 收稿日期:1995-07-04 修回日期:1995-10-23 出版日期:1996-04-10 发布日期:1996-04-10

Effect of pH and Electrolytes on Stability of Aluminium Magnesium Hydroxide Positive Sol

Hou Wanguo, Yu Yaoqin, Zhang Chunguang, Wu Lianyong, Wang Guoting   

  1. Institute of Colloid and Interface Chemistry, Shandong University, Jinan 250100
  • Received:1995-07-04 Revised:1995-10-23 Published:1996-04-10 Online:1996-04-10

摘要: 研究了pH和无机电解质对氢氧化铝镁正电溶胶稳定性的影响,发现在pH5~10范围内,该溶胶比较稳定地存在;pH<5时,发生酸溶解作用;pH>10.5时,因发生表面羟基的脱质子化而使溶胶不稳定性。阴离子的价数越高,聚沉能力越大。降低pH时,NaCl、NaNO3、Na2CO3和Na3PO4的聚沉能力下降,而Na2SO4变化不大。一价阴离子的聚沉能力大小顺序是:Br->I->NO3->Cl-.阳离子的价数越高,对氢氧化铝镁正电溶胶的稳定作用越强。聚沉动力学研究表明,一价阴离子电解质的聚沉过程可分为快速聚沉和慢速聚沉,在慢速聚沉区,稳定率与电解质浓度成良好的线性关系,这与经典的慢速聚沉理论相一致。还改进了聚沉作用的静态研究方法。

关键词: 氢氧化铝镁, 正电溶胶, 聚沉作用, 分散体系

Abstract: The effect of pH and electrolytes on stability of aluminium magnesium hydroxide positive sol was studied. It was found that aluminium magnesium hydroxide positive sol is stable in the range of pH 5~10; the acidic dissolution of the sol occurs at pH<5, and the surface hydroxys of sol particles lose hydrions to lose stability at pH>10.5. The higher the valence number of anions, the stronger the coagulation ability for the positive sol. Decreasing the pH, the coagulation abilities of monovalent anions (Cl-, NO3-) and CO32-, PO43- decrcase, but the coagulation ability of SO42- is almost not varied. The higher the valence number of cations, the stronger the stability for positive sol. The studies of coagulation kinetics showed that the coagulation process of monovalent anions may be divided into rapid and slow coagulation. In slow coagulation region, the stability ratio are of good linear relationship with concentration of electrolytes in agreement with classical slow coagulation theory. In addition,the static method for measuring coagulation ability has been improved.

Key words: aluminium magnesium hydroxide, positive sol, coagulation, dispersion