中华医学超声杂志

应用化学 ›› 1995, Vol. 0 ›› Issue (5): 33-36.

• 研究论文 • 上一篇    下一篇

高碲酸合铜(Ⅱ,Ⅲ)配合物的合成和性质

吴明, 苏锵, 胡刚, 杜森林, 任玉芳   

  1. 中国科学院长春应用化学研究所稀土化学与物理开放实验室, 长春 130022
  • 收稿日期:1994-11-17 修回日期:1995-03-06 出版日期:1995-10-10 发布日期:1995-10-10
  • 基金资助:
    国家自然科学基金资助课题

Pteparation and Properties of Telluratocuprate(Ⅱ,Ⅲ)Complexes

Wu Mingmei, Su Qiang, Hu Gang, Du Senlin, Ren Yufang   

  1. Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022
  • Received:1994-11-17 Revised:1995-03-06 Published:1995-10-10 Online:1995-10-10

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摘要： 在H6TeO6/KOH水溶液中以臭氧为氧化剂,将二价铜化合物氧化成三价铜化合物,并获得一个新的三价铜化合物Ba4K[Cu(H2TeO6)2](OH)4·6H2O;描述了碱性溶液中"Cu(Ⅲ)/Cu(Ⅱ)"循环伏安图.对铜(Ⅲ)化合物,Na4H[Cu(H2TeO6)2]·17H2O以及相应的铜(Ⅱ)配合物的电子光谱和Cu2pXPS进行了研究,给出了其配位场场强参数和Cu2pXPS的电子结合能.由于价态升高,光电子空穴寿命缩短,Cu2pXPS的谱峰增宽.

关键词: 高碲酸合铜(Ⅱ.Ⅲ)配合物, 臭氧氧化, 循环伏安图, 电子光谱, 光电子能谱

Abstract: Detailed investigation on the preparation and properties of telluratocuprate(Ⅱ,Ⅲ)complexes has been performed.In the solution of H6TeO6/KOH,Cu(Ⅲ)complex wasobtained by adopting ozone as oxidant and a new copper(Ⅲ)compound Ba4K[Cu(H2TeO6)2](OH)4· 6H2O was isolated.The cyclic voltammogram of u Cu(Ⅲ)/Cu(Ⅱ)"couple in alka-line solution was described.According to the electronic spectra and Cu2p XPS of the new Cu(Ⅲ)compound, Na4H[Cu(H2TeO6)2]·17H2O and related Cu(Ⅱ) complexes, the ligandfield parameters and the binding energies of Cu2p3/2 for these Cu(Ⅲ)and Cu(Ⅱ)complexeswere determined.

Key words: telluratocuprate(Ⅱ, Ⅲ)complex, ozone oxidation, voltammogram, electronicspectrum, XPS

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