应用化学 ›› 1995, Vol. 0 ›› Issue (4): 111-113.

• 研究论文 • 上一篇    下一篇

重铬酸铵与明胶光化学反应的光声光谱研究

陈钢进1, 杜浩2, 蔡铁权2, 方健文2   

  1. 1. 浙江师范大学化学系, 金华 321004;
    2. 浙江师范大学物理系, 金华
  • 收稿日期:1994-10-12 修回日期:1995-03-06 出版日期:1995-08-10 发布日期:1995-08-10

Study on the Photochemical reaction of Dichromated Gelatin by Photoacoustic Spectroscopy

Chen Gangiin1, Do Hao2, Cai Tiequan2, Fang Jianwen2   

  1. 1. Department, of Chemistry, Zhejiang Normal University, Jinhua 321004;
    2. Department of Physics, Zhejiang Normal University, Jinhua
  • Received:1994-10-12 Revised:1995-03-06 Published:1995-08-10 Online:1995-08-10

摘要: 重铬酸盐明胶(DCG)是全息照相的重要材料,全息图的形成过程是六价铬在光的激发下与明胶分子的某些基团发生反应,还原为三价铬;三价铬再与明胶分子的某些基团形成配键使明胶交联,产生折射率调制而成像.某些物理、化学参数怎样影响这一过程尚不十分清楚.

关键词: 重铬酸盐明胶, 光化学反应, 光声光谱

Abstract: The photochemical reaction of dichromated gelatin was studied by laser photoa-coustic spectroscopy,Results show that the solid-state reaction of the dichromate withgelatin obeys Watanabe-Westheimer reaction scheme. The photosensitivity of dichromatedgelatin is dependent on pH and concentration of dichromate solution.

Key words: dichromated gelatin, photochemical reaction, laser photoacoustic spectrum