应用化学 ›› 1995, Vol. 0 ›› Issue (3): 115-116.

• 研究论文 • 上一篇    下一篇

聚铝氨烷-钌-镧对1-己烯醛化反应的催化作用

杨荣华1, 吴晓龙2, 黄美玉3, 江英彦3   

  1. 1. 黑龙江大学化学系, 哈尔滨 150080;
    2. 黑龙江省科学技术协会, 哈尔滨;
    3. 中国科学院化学研究所, 北京
  • 收稿日期:1994-09-21 修回日期:1995-01-20 出版日期:1995-06-10 发布日期:1995-06-10

Catalytic Hydrofotmylation of 1-Hexene by Polyalumazane-Ruthenium-Lanthanum Complex

Yang Ronghua1, Wu Xiaolong2, Huang Meiyu3, Jiang Yingyan3   

  1. 1. Department of Chemistry, Heilongjiang University, Harbin 150080;
    2. Heilongjiang Association for Science and Technology, Harbin;
    3. Institute of Chemistry, Chinese Academy of Sciences, Beijing
  • Received:1994-09-21 Revised:1995-01-20 Published:1995-06-10 Online:1995-06-10

摘要: 醛化反应通常以羰基铑、羰基铐, 羰基钴及淡基钉等作催化剂.高分子-金属配合物,如聚铝氨烷、聚钛氮烷、聚锡氮烷等无机高分子的铑及钌一钴配合物,对烯烃醛化反应的催化性能往往优于小分子的羰基金属配合物.本文研究了聚铝氨烷一钌一斓双金属配合物对1-己烯醛化反应的催化作用.

关键词: 高分子催化剂, 己烯, 醛化, 聚铝氨烷-钌-镧配合物

Abstract: The catalytic hydroformylation of 1-hexene by polyalumazane-ruthenium-lan-thanum complex has been investigated.Lanthanum in the complex plays as a promoter of thecatalyst.

Key words: polymer catalyst, hexene, hydroformylation, polyalumazane-ruthenium-lantha-num complex