中华医学超声杂志

应用化学 ›› 1995, Vol. 0 ›› Issue (1): 38-42.

• 研究论文 • 上一篇    下一篇

三羰基全甲基硅基环戊二烯基钼衍生物的合成与表征

邝代治1, 周秀中2   

  1. 1. 衡阳师范专科学校化学系, 衡阳 421008;
    2. 南开大学化学系, 天津
  • 收稿日期:1994-04-19 修回日期:1994-09-06 出版日期:1995-02-10 发布日期:1995-02-10
  • 基金资助:
    元素有机化学所国家重点实验室资助课题

Synthesis and Characterization of Tricarbonylhexamethylsilylcyclopentadienyl Molybdenum Derivatives

Kuang Daizhi1, Zhou Xiuzhong2   

  1. 1. Department of Chemistry, Hengyang Teacher's College, Hengyang 421008;
    2. Department of Chemistry, Nankai University, Tianjin
  • Received:1994-04-19 Revised:1994-09-06 Published:1995-02-10 Online:1995-02-10

PDF

319

被引次数

11 | 2

摘要： 通过三羰基(五甲基二硅基)环戊二烯基钼负离子盐与卤代烃(EtI、PhCH2Cl、ClCH2COOEt、I(CH2)4I)进行烷基化反应合成其烷基钼化合物.用六甲基三硅二氧烷桥联双(三羰基环戊二锑基钼)负离子经冰醋酸处理、硫酸铁氧化偶联成钼-钼键双核化合物,经碘裂解后钼-钼键生成六甲基三硅二氧烷桥联双(三羰基环戊二烯基碘钼)比合物.以元素分析、IR和1HNMR谱表征了化合物的结构.

关键词: 五申基二硅基环戊二烯, 六甲基三硅二氧烷桥联双环戊二烯, 钼负离子, 烷基化反应, 氧化偶联

Abstract: The alkyl-molybdenum compounds were synthesized via reactions of tricar-bonylpentamethyldisilanyicyclopentadienyl molybdenum anion saIt with alkyl halide (ethyl-chloroacetate,benzyl chloride,ethyliodide,1,4-diiodobutane).The hexamethyltrisiloxyl-bridged-bis (tricarbonylcyclopentadienyl molybdenum anion salt) was treated with glacialacetic acid and followed reacted with ferric sulfate to produce the oxidative coupling molybd-num-molybdenum dinuclear compound.HexamethyItrisiloxyl-bridged bis (tricarbonyl-cyclopentadienyliodo-molybdenum) compound was formed by cleavage of molybdenum-molybdenum bond with iodine. The structures of title compounds were characterized by ele-mental analysis,IR and 1H NMR measurements.

Key words: pentamethy disilany cyclopentadiene hexamethy trisiloxy bridged biscycl open-tadiene, molybdenum anion, alkylation reaction, oxidative coupling

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