中华医学超声杂志

应用化学 ›› 1992, Vol. 0 ›› Issue (3): 37-40.

• 研究论文 • 上一篇    下一篇

β-二酮缩β-丙氨酸希夫碱的锰(Ⅲ)配合物

陈克, 吴志平   

  1. 浙江大学化学系, 杭州 310027
  • 收稿日期:1991-04-04 修回日期:1991-08-20 出版日期:1992-06-10 发布日期:1992-06-10

MANGANESE(Ⅲ) COMPLEXES OF SCHIFF BASES DERIVED FROM β-DIKETONE AND β-ALANINE

Chen Ke, Wu Zhiping   

  1. Department of Chemistry, Zhejiang university, Hangzhou 310027
  • Received:1991-04-04 Revised:1991-08-20 Published:1992-06-10 Online:1992-06-10

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摘要： 合成了锰(Ⅲ)的双核配合物Mn2(Hacala-β)2(O2CMe)4和三核配合物Mn3O(bzala-β)2(O2CMe)3·4H2O,其中Hacala-β-和bzala-β2-分别是乙酰丙酮缩β-丙氨酸和苯甲酰丙酮缩β-丙氨酸希夫碱负离子。用电导率、磁化率、热分析、红外及紫外可见光谱等对它们的结构和性质进行了研究。

关键词: 锰(Ⅲ)配合物, 希夫碱, β-二酮, β-丙氨酸

Abstract: Di and trinuclear manganes(Ⅲ) complexes:Mn2 (Hacala-β)2 (O2CMe)4 and Mn3O(bzalaβ)2(O2CMe)3·4H2O,where Haeala-β- and bzala-β2- are the Schiff base anions prepared by condensing β-alanine with acetylacetone and benzoylaeetone respectively, have been synthesized and studied by electronic conductivity, magnetic susceptibility, thermal analyses, IR and UV-Vis spectra measurements.

Key words: manganese (Ⅲ)complex, Schiff base, β-diketone, β-alanine

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