中华医学超声杂志

应用化学 ›› 1991, Vol. 0 ›› Issue (6): 33-36.

• 研究论文 • 上一篇    下一篇

尼龙-1010 SAXS研究

莫志深1, 杨宝泉1, 薛小芙1, 孟昭富2, 王煜明2   

  1. 1. 中国科学院长春应用化学研究所, 高分子物理开放实验室, 长春 130022;
    2. 吉林大学材料科学研究所, 长春
  • 收稿日期:1990-09-17 修回日期:1991-01-09 出版日期:1991-12-10 发布日期:1991-12-10

SMALL-ANGLE X-RAY SCATTERING STUDIES ON NYLON-1010

Mo Zhishen1, Yang Baoquan1, Xue Xiaofu1, Meng Zhaofu2, Wang Yuming2   

  1. 1. Laboratory of Polymer Physics, Chang chun Institute of Applied Chemistry, Academia Sinica, Changchun 130022;
    2. Materials Science Institute, Jilin University, Changchun 130023
  • Received:1990-09-17 Revised:1991-01-09 Published:1991-12-10 Online:1991-12-10

PDF

353

被引次数

2

摘要： 用一维电子密度相关函数方法,分析了国产尼龙-1010不同拉伸比时的SAXS现象,由实验相关函数曲线可算得长周期(L),中间层厚(dtr),片晶层厚(dσ),非晶层厚(Aσ),平均片层厚(d),积分不变量(Q),比内表面Os以及(ηc-ηa)等数值及其变化规律。实验结果表明尼龙-1010的结晶结构是由结晶层、非晶层以及结晶-非品中间层三部分组成。

关键词: 尼龙-1010, 小角X-射线散射, 一维电子密度相关函数, 结晶-非晶中间层, 长周期

Abstract: The structures of Nylon-1010 with different draw ratio have been investigated by usingSmall-Angle X-ray Scattering(SAXS). It is shown that by using a simple geometrical cons-truction the following structure parameters can be directly derived from the correlation func-tion the long period(L), the thickness of the crystalamorphous interphase (dtr), the lamellarthickness(d), the "invariant"(Q), the specific inner surface (Os), and the electron densitydifference between the core of the crystallites and the amorphors matrix(ηc - ηa). The crystalline Nylon-1010 is probably consisted of three-phases: a crystalline layer, anamorphous layer and a transition zone between amorphous(Ao) and crystalline layer(do).

Key words: Nylon-1010, SAXS, one-dimensional electron density correlation function, crystal-amorphous interphase, long period

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