应用化学 ›› 1991, Vol. 0 ›› Issue (2): 69-71.

• 研究简报 • 上一篇    下一篇

热致变色化合物TiO[VO(SO4)2(H2O)3]·2H2O的合成及其性能

吴道澄1, 周世光2   

  1. 1. 第四军医大学化学教研室, 西安 710033;
    2. 国防科技大学应用化学系, 长沙
  • 收稿日期:1990-02-19 修回日期:1990-07-25 出版日期:1991-04-10 发布日期:1991-04-10

A NOVEL THERMOCHROMIC COMPOUND TiO[VO(SO4)2(H2O)3]2H2O

Wu Daocheng1, Zhou Shiguang2   

  1. 1. Department of Chemistry, the Fourth Military Medical University, Xian 710033;
    2. Department of Applied Chemistry, National University of Defence Technology, Changsha
  • Received:1990-02-19 Revised:1990-07-25 Published:1991-04-10 Online:1991-04-10

摘要: 热致变色示温材料具有操作方便,测温范围广和不需要复杂仪器等优点,因而广泛用于宇航事业、热记录材料及传感器等。钒为我国丰产元素,钒化合物的热致变色研究报导不多[1]。本文报导氧钒(Ⅳ)化合物作为热致变色材料的探索。

关键词: 热致变色, 氧钒化合物

Abstract: The title compound was prepared by heating V2O5 and K2TiO(C2O4)2·2H2O in sulfuricacid solution.Its composition was ascertained by elemental analysis.The compound changesfrom green to yellow at 418℃.The mechanism of thermochromism is ascribed to thedehydration of the coordinated water as confirmed by ESR, TG, DTA and IR results.

Key words: thermochromism, vanadium oxide compound