应用化学 ›› 1990, Vol. 0 ›› Issue (2): 92-94.

• 研究简报 • 上一篇    下一篇

醇盐法制备稀土化合物超微粉末

景晓燕, 洪广言, 李有谟   

  1. 中国科学院长春应用化学研究所 长春 130022
  • 收稿日期:1989-07-22 修回日期:1989-11-03 出版日期:1990-04-10 发布日期:1990-04-10

PREPARATION OF ULTRAFINE POWDERS OF RARE EARTH COMPOUNDS BY ALCOXIDE METHOD

Jing Xiaoyan, Hong Guangyan, Li Youmo   

  1. Changchun Institute of Applied Chemistry, Academia Sinica, Changchum 130022
  • Received:1989-07-22 Revised:1989-11-03 Published:1990-04-10 Online:1990-04-10

摘要: 稀土元素具有广泛的用途,在大多数的应用中其效果都与原料的纯度、粒度、粒经分布范围等因素有关。由于超微粉末的比表面积大、化学活性高,因此可以预料,若将稀土化合物制成超微粉末,会使它的催化性能及在各种材料中的性能有明显的改变,也可使稀土有新的、更高的应用价值。

关键词: 稀土氢氧化物, 稀土氧化物, 超微粉末, 醇盐法

Abstract: Ultrafine powders of hydroxides and oxides of thirteen rare earths have been praparedby alcoxide method. The size of the powder particle was less than 0.05μm by TEM observa-tion. The powders obtained from Jight rare earths are different in shapes from those fromheavy rare earths and are easier to be dispersed. XRD determination showed that the ultra-fine powders of some rare earth hydroxides are crystalline, while the powders of the oxidesare all crystalline.

Key words: hydroxide of rare earth, oxide of rare rare earth, ultrafine powder, preparation