应用化学 ›› 1987, Vol. 0 ›› Issue (2): 26-30.

• 研究论文 • 上一篇    下一篇

Co60γ-射线辐照对熔融结晶聚乙烯形态的影响——Ⅰ.形态的保持和破坏效应

王国英, 陈南羽, 姜炳政   

  1. 中国科学院长春应用化学研究所
  • 收稿日期:1985-12-21 修回日期:1986-04-26 出版日期:1987-04-10 发布日期:1987-04-10

THE EFFECT OF Co60γ-RAY RADIATION ON THE MORP?OLOGY OF MELT-CRYSTALLIZED POLYETHYLENE Ⅰ.MORPHOLOGICAL PRESERVATION AND DAMAGE

Wang Guoying, Chen Nanyu, Jiang Bingzheng   

  1. Changchun Institute of Applied Chemistry, Academia Sinica
  • Received:1985-12-21 Revised:1986-04-26 Published:1987-04-10 Online:1987-04-10

摘要: 本系列工作的此部分系用小角激光光散射,小角χ光散射,广角χ光衍射等技术考察了高密度聚乙烯的球晶、片晶和微晶等宏观和微观结构在不同辐照条件下的行为和变化,发现辐照交联对聚乙烯球晶结构有保持效应,且这种效应随辐照剂量的增大而加强;辐照交联对聚乙烯的片层结构也有保持效应,但对片晶内部却有破坏效应,辐照导致了聚乙烯结晶的晶胞膨胀,用"片晶内部破坏"机理解释χ光小角散射积分不变量随辐照剂量单调下降比用"片晶表面破坏"机理解释更为合适。

Abstract: The effect of Co60γ- ray radiation on spherulites, lamellae and crystallites etc.of melt-cry-stallized high density polyethylene was studied with small angle light scattering,small anglex-tay scattering (SAXS) and wide angle x-ray diffraction techniques. It has been shown that there is a tendency to preserve the contour and optical anisotropy of spherulites in irradiation samples afrer melting and recrystallization due to radiation-in-duced cross-linking. The higher the radiation dose. the stronger the tendency to preserve.Lamellae preserve their own profile, although crystalline damage takes place within lamellae due to irradiation. The damage of the crystalline lamellae cannot be explained vrith "lamellae surface damage" mechanism suggested by Keller. A "lamellae cored damage" mechanism has to be suggested and could give a more satisfactory explaination of the SAXS results.