应用化学 ›› 1986, Vol. 0 ›› Issue (4): 48-50.

• 研究简报 • 上一篇    下一篇

8-氧-二喹啉并[5,6-b;6′,5′-e]-碘六环盐的合成

张功成, 谭镇, 李裕林   

  1. 兰州大学有机化学研究所
  • 收稿日期:1985-11-01 修回日期:1986-01-26 出版日期:1986-08-10 发布日期:1986-08-10
  • 通讯作者: 张功成
  • 基金资助:
    中国科学院科学基金资助课题

SYNTHESIS OF THE 8-OXO-DIQUINO(5,6-b;6′,5′-e)-PYRIODONIUM COMPOUND

Zhang Gongcheng, Tan Zhen, Li Yulin   

  1. Institute of Organic Chemistry, Lanzhou University
  • Received:1985-11-01 Revised:1986-01-26 Published:1986-08-10 Online:1986-08-10

摘要: 在已合成的数十种碘杂环类化合物中,绝大多数是二苯并碘杂环化合物,而含生物碱的二喹啉醚类碘杂环化合物至今未见报道。

Abstract: A new iodine heterocyclic compound, 8-oxo-diquino(5, 6-b; 6′, 5′-e)-pyriodonium [Ⅲ] compound, white needles prims(m•p•221-2℃),was prepared in about 68% yield by treating 6,6′-diquinolyl oxide[Ⅱ] with iodosyl sulfate in concentrated sulfuric acid,following by pyridine [Ⅲ] The structures of [Ⅱ] and [Ⅲ] were confirmed by IR,~1HNMR, MS and elemental analysis.