应用化学 ›› 1986, Vol. 0 ›› Issue (4): 22-25.

• 研究论文 • 上一篇    下一篇

端羟基液体聚丁二烯的流变性质

江家奇, 王兰琴   

  1. 中国科学院长春应用化学研究所
  • 收稿日期:1985-05-24 修回日期:1985-10-31 出版日期:1986-08-10 发布日期:1986-08-10
  • 通讯作者: 江家奇

RHEOLOGICAL PROPERTY OF LIQUID HYDROXY-TERMINATED POLYBUTADIENE

Jiang Jiaqi, Wang Lanqin   

  1. Changchun Institute of Applied Chemistry, Academia Sinica
  • Received:1985-05-24 Revised:1985-10-31 Published:1986-08-10 Online:1986-08-10

摘要: 本文研究了端羟基液体聚丁二烯(丁羟)的流变性质,它是剪切速率、温度和分子量的函数。测量是在HAAKE RV2锥板式粘度计上进行的,温度15—70℃,剪切速度0—2,275s-1。 当丁羟本体粘度小于1Pa•s,剪切速率低于650s-1时,其流动行为基本为牛顿型,在其它条件下则为非牛顿型。当丁羟分子量在1,000—5,600范围内,其本体粘度与温度关系符合经验公式:logηa=A+B/T。我们也确立了本体粘度与数均分子量的关系,在20℃时ηa=2.09×10-8Mn2•52,在25℃时为ηa=1.14×10-8Mn2•55

Abstract: The rheological property of liquid hydroxy-terminated polybutadiene (HTPB) was studied as a function of shear rate,temperature and its molecular weight. Measurements were made in the temperature from 15 to 70℃ and shear rate range from 0 to 2279s-1. The flow behavior of HTPB is found to be essentially Newtonian. When bulk vis-cosity is below 1 Pa. sec. and shear rate below 650 s-1., but it is also a non-Newto-nian under other conditions.The results concerning the relationship between bulk visco-sity and temperature are following the empirical equation:logηa=A+B/T, when the molecular weight of HTPB is 1,000—5,600.The relation between bulk viscosity and number average molecular weight was established as ηa=2.09×10-8Mn2•52 and ηa=1.14×10-8Mn2•55 at 20 and 25℃, respectively.