应用化学 ›› 1985, Vol. 0 ›› Issue (3): 77-80.

• 研究简报 • 上一篇    下一篇

碱催化合成N-羟甲基丙烯酰胺的动力学

朱静安, 项素云, 段春田, 张立萍   

  1. 大连工学院
  • 收稿日期:1984-10-04 修回日期:1985-03-12 出版日期:1985-09-10 发布日期:1985-09-10

KINETICS OF N-METHYLOLACRYLAMIDE SYNTHESIS WITH NaOH AS CATALYST

Zhu Jingan, Xiang Suyun, Duan Chuntian, Zhang liping   

  1. Dalian Institute of Technology
  • Received:1984-10-04 Revised:1985-03-12 Published:1985-09-10 Online:1985-09-10

摘要: N-羟甲基丙烯酰胺(N-MAM)具有可聚合的双键和可缩合的羟基,能进一步与其它烯烃化合物反应生成共聚物及交联产物,是一种有重要经济价值的水溶性功能高分子单体。

Abstract: The kinetics of N-MAM synthesized from formaldehyde and acrylamide with NaOH as catalyst in a water solution system and the effect of the amount of catalyst used have been studied. It was found that the reaction rate increased with the increase of reaction temperature and pH of the system. A relative equation between pH and reaction rate constant was obtained. The activation energy of the reaction was calculated.