应用化学 ›› 1985, Vol. 0 ›› Issue (1): 48-53.

• 研究论文 • 上一篇    下一篇

内应力对顺-1,4-聚丁二烯结晶的影响

余赋生, 徐洋, 张琴   

  1. 中国科学院长春应用化学研究所
  • 收稿日期:1984-04-07 修回日期:1984-08-16 出版日期:1985-03-10 发布日期:1985-03-10

THE EFFECT OF INTERNAL STRESS ON THE CRYSTALLIZATION OF CIS-1,4 POLYBUTADIENE

Yu Fusheng, Xu Yang, Zhang Qin   

  1. Changchun Institute of Applied Chemistry, Academia Sinica
  • Received:1984-04-07 Revised:1984-08-16 Published:1985-03-10 Online:1985-03-10

摘要: 本工作用线膨胀仪观察了顺-1,4-聚丁二烯(PB)生胶恒温及等速降温条件下的结晶行为,发现某些胶样在结晶前出现长度增加,而加热至结晶融化时出现长度收缩,随样品退火程度的增加所述现象逐渐减小,直至消失。本工作用含凝胶样品受外力作用后能产生内应力并生成束状结晶的模型来进行解释,其结果得到DSC的验证。

Abstract: The isothermal crystallization behavior of cis-1, 4polybutadiene raw rubber was studied at depressed or elevated temperature by means of a linear dilatometer. It was found that the length of some gel-containing samples increases at the beginning of crystallization, and it decreases until the crystal is melted completely. These abnomal phenomena disappear gradually with the process of annealing of the sample. In this paper a model of the gelcontaining sample is proposed which may preserve the internal stress by adding an external force. Owing to the internal stress preserved in the sample, the oriented gel parts form a fibrillar crystal at first stage, which lengthens the sample,then the spherical crystal formed in the sol parts reduces the length of the sample. Such interpretation is further confirmed by DSC experiments.