中华医学超声杂志

应用化学 ›› 1985, Vol. 0 ›› Issue (1): 19-23.

• 研究论文 • 上一篇    下一篇

茜素绿的电还原

刘雁呜1, 俞泽穆2, 汪尔康2   

  1. 1. 山西大学化学系;
    2. 中国科学院长春应用化学研究所
  • 收稿日期:1984-02-13 修回日期:1984-10-11 出版日期:1985-03-10 发布日期:1985-03-10

ELECTROREDUCTION OF ALIZARIN GREEN

Liu Yanming1, Yu Zemu2, Wang Erkang 2   

  1. 1. Departmen of Chemistry, Shanxi University;
    2. Changchun Institute of Applied Chemistry, Academia Sinica
  • Received:1984-02-13 Revised:1984-10-11 Published:1985-03-10 Online:1985-03-10

PDF

384

被引次数

1

摘要： 本文用普通极谱、脉冲极谱、循环伏安等方法研究了茜素绿的电还原。在Britton-Ro-binson缓冲溶液中,随pH不同,茜素绿先后共可产生4个极谱波。其中第一、第四波为吸附波。第一、二波之和相当于从氧化态到中间态的还原;第三波相当于从中间态到还原态的还原。根据一系列实验结果确定了各波的性质,提出一带有岐化反应的电还原机理,并测定了茜素绿的离解常数。

Abstract: The electroreduction of alizarin green has been studied by polarographyand cyclic voltammetry. One to four waves of alizarin green appear depending on pH in Britton-Robinson buffer solution. Wave Ⅰ and Wave Ⅰ V are of adsorption character.Thesum of wave Ⅰ and wave Ⅱ is related to the electroreduction of alizaringreen from its oxidized form to an intermediate, while wave Ⅲ is due to thefurther reduction. An electroreduction mechanism of alizarin green involvingdisproportion reaction has been proposed.

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