应用化学 ›› 1983, Vol. 0 ›› Issue (1): 73-78.

• 研究论文 • 上一篇    下一篇

水力冲灰防垢机理的研究

卢云锦, 江善根, 朱卫   

  1. 南京大学络合物研究所
  • 收稿日期:1983-06-06 修回日期:1983-07-15 出版日期:1983-12-10 发布日期:1983-12-10

A STUDY ON THE MECHANISM OF ANTI-INCRUSTATION IN THE COURSE OF CLEANING OFF THE DUSTY WATER BY FORCED WATER STREAM

Lu Yunjin, Jiang Shangen, Zhu Wei   

  1. Department of Chemistry, Nanjing university
  • Received:1983-06-06 Revised:1983-07-15 Published:1983-12-10 Online:1983-12-10

摘要: 用X-射线衍射分析、扫描电子显微镜和化学分析等方法研究了硬垢和水渣的形态与组成,发现管道中形成的硬垢有很好的取向,可以看作是一块内部缺陷很多,存在大量夹杂物的大晶体。若采用水射器强力搅拌灰水,使它的pH值>11,由于同离子效应,很快析出大量碳酸钙小晶体,同时由于无定形的氢氧化镁随着析出,附着在碳酸钙小晶体周围,限制了碳酸钙晶粒长大,结果使沉淀的小晶体取向杂乱无章,生成疏松的水渣,容易被水冲走,在管道中就不会形成硬垢。

Abstract: The morphology and the composition of the hard incrustation stuck on the inner wall of pipeline and the water residue have been studied using methods of x-ray diffraction analysis,scanning electron microscope, chemical analysis, etc.. It was found that the incrustation had a preffered orientation and might be considered as a large crystal of CaCO3 with a lot of defects and inclusions in it.The method of vigorous stirring the dusty water with forced water stream is often used in order to prevent the formation of the incrustation.It was found that under such conditions the pH would become greater than 11 and a lot of small crystals of CaCO3 will be formed quic-kly due to the common ion effect, at the same time the amorphous Mg(OH)2 is precipited, which being adhered to the surfaces of the small crystals will stop the further growth of CaCO3 crystal. As a result, the orien-tation of the small crystals becomes impossible and a loose water residue remains,which can be taken away easily by forced running water.