应用化学

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一种电荷转移型咔唑苯腙衍生物的合成及其发光行为

李俊芬1,李晋增1,张彩虹1,韩玉英1,秦曦1,董川2*   

  1. (1.山西大学化学化工学院 太原 030006;2.山西大学环境科学与工程研究中心 太原 030006)
  • 收稿日期:2012-12-10 修回日期:2013-01-21 出版日期:2013-10-10 发布日期:2013-10-10
  • 通讯作者: 董川,教授; Tel/Fax:0351-7018613; E-mail:dc@sxu.edu.cn; 研究方向:光谱分析及药物分析
  • 基金资助:
    国家自然科学基金(20575037,21105060)山西省自然科技基金(2010011013-1,2012011007-2)资助项目

Synthesis and Luminescence Behavior of a Novel Charge Transfer Compound Containing Carbazole Phenylhydrazone

LI Junfen1, LI Jinzeng1, ZHANG Caihong1, HAN Yuying1, QIN Xi1, DONG Chuan2*   

  1. (1.School of Chemistry and Chemical Engineering,Shanxi University,Taiyuan 030006,China;
    2.Research Center of Environmental Science and Engineering,Shanxi University,Taiyuan 030006,China)
  • Received:2012-12-10 Revised:2013-01-21 Published:2013-10-10 Online:2013-10-10
  • Contact: dong

摘要: 合成了具有强电子给体和拉电子能力基团的新化合物:9-乙基-3-咔唑亚甲基-(2,4-二硝基)苯腙,研究了其光谱性质和光物理行为。 结果表明,化合物在溶液中,随着溶剂极性的增大,发生了分子内电子转移,激发态和基态的偶极矩差值(μE-μG)为 4.530 D,并在强极性溶剂中出现了有趣的双荧光发射。 随着其浓度增大,会形成二聚或多聚体,荧光发射发生红移。

关键词: 咔唑腙类化合物, 分子内电荷转移, 溶剂极性

Abstract: A novel compound, containing a strong electron donor and a strong electron acceptor,3-((2-(2,4-dinitrophenyl)hydrazono)methyl)-9-ethyl-9-H-carbazole, was synthesized. Its spectral property and photo-physical behavior were studied. Intermolecular charge transfer occurred from N-ethylcarbazole to NO2— with the increase of the solvent polarity. Double fluorescence emission was observed in strong polarity solvent. Change of dipole moment between the ground state and the excitation state was 4.53 D. Dimmer or polymer was formed at high concentration and the emission wavelength was red shifted.

Key words: Carbazole hydrazone compounds, Intramolecular charge transfer, Solvent polarity

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