应用化学 ›› 2010, Vol. 27 ›› Issue (03): 249-256.DOI: 10.3724/SP.J.1095.2010.90383

• 综合评述 •    下一篇

氯苯类污染物在高层大气环境中形成的可能性

曹洁1,崔义1,刘淑莹2*   

  1. (1.北京理工大学化学系 北京;2.中国科学院长春应用化学研究所 长春 130022)
  • 收稿日期:2009-06-08 修回日期:2009-08-20 出版日期:2010-03-10 发布日期:2010-03-10
  • 通讯作者: 刘淑莹,女,研究员,博士生导师; E-mail:syliu19@yahoo.com.cn; 研究方向:有机质谱基础及应用
  • 基金资助:
    “九七三”计划前期研究专项(2008CB417204)吉林省科技发展计划基金(20060576)和环境化学与生态毒理学国家重点实验室开放基金(KF2008-02)资助项目

Investigation on the formation mechanism of chlorobenzenes in the atmosphere

CAO Jie1, CUI Xi1, LIU Shu-Ying2*   

  1. (1.Department of Chemistry,Beijing Institute of Technology,Beijing;
    2.Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022)
  • Received:2009-06-08 Revised:2009-08-20 Published:2010-03-10 Online:2010-03-10

摘要:

简要地总结了大气离子与自由基反应的研究进展和以氯苯为目标产物的气相离子-分子反应的质谱研究。 根据大气层状结构图、高层大气的特点以及相关的研究结果,提出了氯苯类污染物的形成不排除是大气化学反应尤其是离子反应产物的观点。 对进一步研究大气中氯苯类污染物的生成机制和控制具有重要意义。

关键词: 氯苯类污染物, 质谱技术, 离子-分子反应

Abstract:

Research on the gas-phase radical/ion chemistry was briefly summarized. Emphasis was given to the application of mass spectrometric technique to ionmolecule reactions between halocarbocations and aromatic compounds which gave rise to chlorobenzenes as one of the targeted products. That chlorobenzenes were readily formed in the mass spectrometer implied that chlorobenzenes in the atmosphere should not exclude the possibility of ion/radical chemistry reactions. The environmental significance of such reactions was also explored.

Key words: chlorobenzenes, mass spectrometry, gas phase ion-molecule reactions

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