Preparation of Fly Ash-based ZSM-5 Zeolite Molecular Sieve and Hydrogen Storage Properties

doi:10.19894/j.issn.1000-0518.220331

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (7): 995-1003.DOI: 10.19894/j.issn.1000-0518.220331

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Preparation of Fly Ash-based ZSM-5 Zeolite Molecular Sieve and Hydrogen Storage Properties

Cong-Hui MIAO, Dilinuer AILI, Zheng-Kun LIAO, Jing-Shan LU, Qing-Hua LIU, Jiang-Yuan LI, Nulahong AISHA()

State Key Laboratory of Carbon-Based Energy Chemistry and Utilization，Xinjiang University and Ministry of Science and Technology，Xinjiang Key Laboratory of Coal Clean Transformation and Chemical Process，College of Chemical Engineerring，Xinjiang University，Urumqi 830017，China

Received:2022-10-12 Accepted:2023-06-02 Published:2023-07-01 Online:2023-07-19
Contact: Nulahong AISHA
About author:aisa705@163.com
Supported by:
the Natural Science Foundation of Xinjiang Uygur Autonomous Region （Joint Fund）(2002D01C378)

Abstract

Abstract:

In recent years， with the continuous growth of coal-fired power generation in China， as the most important solid waste of coal-fired power plants， the emission of fly ash has also increased sharply with the growth of coal consumption. Fly ash is a by-product of burning coal in coal-fired power stations. Large amounts have been discharged from power plants and dumped on reclaimed land or into the sea， posing potential risks to the environment around these areas and causing serious social and environmental problems. On the other hand， the content of aluminum and silicon elements in fly ash is very high， which has a very high extraction value. Due to the special physical and chemical properties of hydrogen， physical adsorption storage of hydrogen energy has the advantages of safety and reliability， rapid adsorption and desorption of hydrogen under mild conditions. In this paper， ZSM-5 zeolite with high crystallinity is directly synthesized by hydrothermal synthesis using fly ash pretreatment and its hydrogen storage performance is studied.

Key words: ZSM-5, Solid waste utilization, Fly ash, Acid treatment, Crystallization time, Hydrogen storage performance

CLC Number:

O613.7

Cong-Hui MIAO, Dilinuer AILI, Zheng-Kun LIAO, Jing-Shan LU, Qing-Hua LIU, Jiang-Yuan LI, Nulahong AISHA. Preparation of Fly Ash-based ZSM-5 Zeolite Molecular Sieve and Hydrogen Storage Properties[J]. Chinese Journal of Applied Chemistry, 2023, 40(7): 995-1003.

Figures/Tables 14

Fig.1 Flowchart of TP-5076 adsorption

Table 1 XRF analysis of fly ash

Composition	SiO₂	Al₂O₃	Na₂O	CaO	Fe₂O₃	MgO	SO₃	TiO₂
w（element）/%	36.80	15.75	5.70	24.51	6.33	4.07	3.79	0.738

Fig.2 XRD spectrum （A） and SEM images （B） of feed fly ash

Fig.3 Acid rate of different leaching times

Fig.4 Changes in silicon-aluminum ratio under different acid concentration n（Si）/n（Al）（A） and XRF （B）

Fig.5 XRD （A） and crystallinity （B） of ZSM-5 zeolite synthesized at different crystallization times

Fig.6 SEM diagram of ZSM-5 zeolite molecular sieve synthesized at different crystallization times

Fig.7 XRD plot of the effect of adding TEOS on zeolite

Fig.8 Effect of TEOS addition on the silicon to aluminum ratio

Fig.9 SEM plot of the sample after adding TEOS

Fig.10 N2 adsorption/desorption isotherms （A） and the pore-size distributions （B）

Table 2 ZSM-5 specific surface area data

ZSM-5

（commodity）

Fig.11 H2-TPD spectra of ZSM-5 samples at different adsorption pressures （A） without TEOS and （B） with TEOS

Fig.12 Adsorption volume of samples with different adsorption pressures

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Preparation of Fly Ash-based ZSM-5 Zeolite Molecular Sieve and Hydrogen Storage Properties

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