Fabrication of Superhydrophobic-Superoleophobic Surfacesby Facile Solution-Immersion and Surface Coating

doi:10.11944/j.issn.1000-0518.2019.03.180243

Chinese Journal of Applied Chemistry ›› 2019, Vol. 36 ›› Issue (3): 358-366.DOI: 10.11944/j.issn.1000-0518.2019.03.180243

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Fabrication of Superhydrophobic-Superoleophobic Surfacesby Facile Solution-Immersion and Surface Coating

SHI Yanlong(),FENG Xiaojuan,KANG Kai,HOU Yang

College of Chemistry and Chemical Engineering,Key Laboratory of Hexi Corridor Resources Utilization of Gansu Universities,Hexi University,Zhangye,Gansu 734000,China

Received:2018-07-13 Accepted:2018-10-23 Published:2019-03-01 Online:2019-02-28
Contact: SHI Yanlong
Supported by:
Supported by the National Natural Science Foundation of China(No.41761061), the Scientific Research Foundation of the Higher Education Institutions of Gansu Province(No.2016B-091), and the General Program of the Key Laboratory of Hexi Corridor Resources Utilization of Gansu Universities(No.XZ1603)

Abstract

Abstract:

Superhydrophobic-superoleophobic materials have received considerable attention due to their wide potential applications in the fields of anti-fouling, water-proof and oil-proof. In this paper, superhydrophobic-superoleophobic zinc spheres are first prepared by immersing the zinc spheres into the solution of perfluorooctanoic acid, and then the superhydrophobic-superoleophobic surfaces are obtained by pasting the obtained superhydrophobic-superoleophobic zinc spheres on substrates of glass, wood, plastic, stainless steel, paper and stone. The contact angles of water and oil droplets on these surfaces all exceed 150°. Zinc spheres react with perfluorooctanoic acid to form zinc perfluorooctanoate, and the coordinate effects of micro/nanometer rough structures and chemical composition with low surface energy of the long fluoroalkyl lead to the formation of superhydrophobicity and superoleophobicity. The research may offer a new idea for the design and fabrication of superamphiphobic materials, as well as their application in self-cleaning, waterproof, oil-proof and anti-contamination.

Key words: superhyrophobicity, superoleophobicity, superamphiphobicity, zinc perfluorooctanoate, solution immersion

SHI Yanlong,FENG Xiaojuan,KANG Kai,HOU Yang. Fabrication of Superhydrophobic-Superoleophobic Surfacesby Facile Solution-Immersion and Surface Coating[J]. Chinese Journal of Applied Chemistry, 2019, 36(3): 358-366.

References

[1]	Barthlott W,Neinhuis C.Purity of the Sacred Lotus, or Escape from Contamination in Biological Surfaces[J]. Planta,1997,202(1):1-8.
[2]	Onda T,Shibuichi S,Satoh N,et al. Super-Water-Repellent Fractal Surfaces[J]. Langmuir,1996,12(9):2125-2127.
[3]	Wang B,Liang W W,Guo Z G,et al. Biomimetic Super-lyophobic and Super-lyophilic Materials Applied for Oil/Water Separation:A New Strategy Beyond Nature[J]. Chem Soc Rev,2015,44:336-361.
[4]	Chu Z L,Seeger S.Superamphiphobic Surfaces[J]. Chem Soc Rev,2014,43(8):2784-2798.
[5]	Chu Z L,Feng Y J,Seeger S.Oil/Water Separation with Selective Superantiwetting/Superwetting Surface Materials[J]. Angew Chem Int Ed,2014,53:2-13.
[6]	Celia E,Darmanin T,Givenchy E T,et al. Recent Advances in Designing Superhydrophobic Surfaces[J]. J Colloid Interface Sci,2013,402:1-18.
[7]	Öner D,McCarthy T J. Ultrahydrophobic Surfaces. Effects of Topography Length Scales on Wettability[J]. Langmuir,2000,16(20):7777-7782.
[8]	Wang R,Hashimoto K,Fujishima A,et al. Photogeneration of Highly Amphiphilic TiO2 Surfaces[J]. Adv Mater,1998,10(2):135-138.
[9]	Tuteja A,Choi W,Ma M L,et al. Designing Superoleophobic Surfaces[J]. Science,2007,318(5856):1618-1622.
[10]	Butt H J,Semprebon C,Papadopoulos P,et al. Design Principles for Superamphiphobic Surfaces[J]. Soft Matter,2013,9(2):418-428.
[11]	Zhang J,Seeger S.Superoleophobic Coatings with Ultralow Sliding Angles Based on Silicone Nanofilaments[J]. Angew Chem Int Ed,2011,50(29):6652-6656.
[12]	Deng X,Mammen L,Butt H J,et al. Candle Soot as a Template for a Transparent Robust Superamphiphobic Coating[J]. Science,2012,335(6064):67-70.
[13]	Jin C,Jiang Y,Niu T,et al. Cellulose-Based Material with Amphiphobicity to Inhibit Bacterial Adhesion by Surface Modification[J]. J Mater Chem,2012,22(25):12562-12567.
[14]	Zhang Z,Zhu X,Yang J,et al. Facile Fabrication of Superoleophobic Surfaces with Enhanced Corrosion Resistance and Easy Repairability[J]. Appl Phys A:Mater Sci Process,2012,108(3):601-606.
[15]	Yao X,Song Y,Jiang L.Superoleophobic Surfaces with Controllable Oil Adhesion and Their Application in Oil Transportation[J]. Adv Funct Mater,2011,21(22):4270-4276.
[16]	Feng X J,Jiang L.Design and Creation of Superwetting/Antiwetting Surfaces[J]. Adv Mater,2006,18(23):3063-3078.
[17]	Bellanger H,Darmanin T,Givenchy E T,et al. Chemical and Physical Pathways for the Preparation of Superoleophobic Surfaces and Related Wetting Theories[J]. Chem Rev,2014,114(5):2694-2716.
[18]	Zhu X,Zhang Z,Xu X,et al. Facile Fabrication of a Superamphiphobic Surface on the Copper Substrate[J]. J Colloid Interface Sci,2012,367(1):443-449.
[19]	Zhao H,Law K Y,Sambhy V. Fabrication, Surface Properties,Origin of Superoleophobicity for a Model Textured Surface[J]. Langmuir,2011,27(10):5927-5935.
[20]	Fujii T,Aoki Y,Habazaki H.Fabrication of Super-Oil-Repellent Dual Pillar Surfaces with Optimized Pillar Intervals[J]. Langmuir,2011,27(19):11752-11756.
[21]	Jin H,Tian X,Ikkala O,et al. Preservation of Superhydrophobic and Superoleophobic Properties upon Wear Damage[J]. ACS Appl Mater Interfaces,2013,5(3):485-488.
[22]	Xu X,Zhang Z,Guo F,et al. Superamphiphobic Self-Assembled Monolayer of Thiol on the Structured Zn Surface[J]. Colloids Surf A,2012,396:90-95.
[23]	Fujii T,Sato H,Tsuji E,et al. Important Role of Nanopore Morphology in Superoleophobic Hierarchical Surfaces[J]. J Phys Chem C,2012,116(44):23308-23314.
[24]	Ganesh V A,Dinachali S S,Raut H K,et al. Electrospun SiO2 Nanofibers as a Template to Fabricate a Robust and Transparent Superamphiphobic Coating[J]. RSC Adv,2013,3(12):3819-3824.
[25]	Zhang M,Zhang T,Cui T.Wettability Conversion from Superoleophobic to Superhydrophilic on Titania/Single-Walled Carbon Nanotube Composite Coatings[J]. Langmuir,2011,27(15):9295-9301.
[26]	Artus G R J,Zimmermann J,Reifler F A,et al. A Superoleophobic Textile Repellent Towards Impacting Drops of Alkanes[J]. Appl Surf Sci,2012,258(8):3835-3840.
[27]	Meng H F,Wang S T,Xi J M,et al. Facile Means of Preparing Superamphiphobic Surfaces on Common Engineering Metals[J]. J Phys Chem C,2008,112(30):11454-11458.
[28]	Xi J M,Feng L,Jiang L.A General Approach for Fabrication of Superhydrophobic and Superamphiphobic Surfaces[J]. Appl Phys Lett,2008,92(5):053102.
[29]	Nishino T,Meguro M,Nakamae K,et al. The Lowest Surface Free Energy Based on —CF3 Alignment[J]. Langmuir,1999,15(13):4321-4323.
[30]	Coulson S R,Woodward I,Badyal J P S. Super-Repellent Composite Fluoropolymer Surfaces[J]. J Phys Chem B,2000,104(37):8836-8840.
[31]	Gao X F,Jiang L.Water-Repellent Legs of Water Striders[J]. Nature,2004,432(7013):36-36.
[32]	Cassie A B D,Baxter S T. Wettability of Porous Surfaces[J]. Faraday Soc,1944,40:546-551.

Fabrication of Superhydrophobic-Superoleophobic Surfacesby Facile Solution-Immersion and Surface Coating

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