Recovery of Organphosphorus Extractants from Water by Anion Exchange Resin

doi:10.11944/j.issn.1000-0518.2018.07.170321

Chinese Journal of Applied Chemistry ›› 2018, Vol. 35 ›› Issue (7): 802-811.DOI: 10.11944/j.issn.1000-0518.2018.07.170321

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Recovery of Organphosphorus Extractants from Water by Anion Exchange Resin

Wenrou SU^a^b,Ji CHEN^a^*(),Yuefeng DENG^a,Maohua YANG^a,Chuanying LIU^a^b

^aState Key Laboratory of Rare Earth Resource Utilization,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China
^bUniversity of Chinese Academy of Sciences,Beijing 100049,China

Received:2017-09-05 Accepted:2017-11-09 Published:2018-07-06 Online:2018-07-06
Contact: Ji CHEN
Supported by:
Supported by the National Natural Science Foundation of China(No.61106017)

Abstract

Abstract:

The adsorption process of anion exchange resin to organphosphorus extractant in water was explored in this work. By comparing the removal of P507(2-ethylhexyl phosphoric acid mono-2-ethylhexyl ester) in water with different anion exchange resins, it is found that D201-OH(macroporous strong basic anion exchange resin) has the strongest ability to remove P507 from water, and the removal rate can reach to 99.24%. Secondly, at pH=1.0, the adsorption of P507 on D201-OH is mainly molecular adsorption and its adsorption isotherm is better fit to the Langmuir model; at pH=5.0, the anion exchange reaction is dominant and its adsorption isotherm is more suitable for the Freundlich model. Furthermore, the adsorption capacity of D201-OH to P507 reaches 99.8% of which in the adsorption equilibrium in 20 min. Kinetic study shows that the pseudo-first-order model(R²>0.99) exhibits a better fit to describe the experimental data and the adsorption rate may be controlled mainly by the film diffusion. Moreover, the adsorption capacity of D201-OH remains above 93% after eight cycles of adsorption-desorption. In summary, D201-OH is an excellent adsorbent for organphosphorus extractants with high stability in the repeated cycle. Therefore, it can be used to recover organphosphorus extractant in the practical production process.

Key words: anion exchange resin, organphosphorus extractant, adsorption mechanism, cycle experiment

Wenrou SU, Ji CHEN, Yuefeng DENG, Maohua YANG, Chuanying LIU. Recovery of Organphosphorus Extractants from Water by Anion Exchange Resin[J]. Chinese Journal of Applied Chemistry, 2018, 35(7): 802-811.

References

[1]	Grandell L,Lehtilä A,Kivinen M,et al. Role of Critical Metals in the Future Markets of Clean Energy Technologies[J]. Renew Energ,2016,95:53-62.
[2]	Su W R,Chen J,Jing Y.Aqueous Partition Mechanism of Organophosphorus Extractants in Rare Earths Extraction[J]. Ind Eng Chem Res,2016,55(30):8424-8431.
[3]	Zhu X Y,Li B,Yang J,et al. Effective Adsorption and Enhanced Removal of Organophosphorus Pesticides from Aqueous Solution by Zr-based MOFs of UiO-67[J]. Adv Colloid Interface Sci,2014,7(1):223-231.
[4]	Islam M A,Sakkas V,Albanis T A.Application of Statistical Design of Experiment with Desirability Function for the Removal of Organophosphorus Pesticide from Aqueous Solution by Low-cost Material[J]. J Hazard Mater,2009,170(1):230-238.
[5]	Chen L,Chen J,Jing Y,et al. Comprehensive Appraisal and Application of Novel Extraction System for Heavy Rare Earth Separation on the Basis of Coordination Equilibrium Effect[J]. Hydrometallurgy,2016,165:351-357.
[6]	Jing Y,Chen J,Chen L,et al. Extraction Behaviors of Heavy Rare Earths with Organophosphoric Extractants:The Contribution of Extractant Dimer Dissociation, Acid Ionization, and Complexation. A Quantum Chemistry Study[J]. J Phys Chem B,2017,121(12):2531-2543.
[7]	Guivarch E,Oturan N,Oturan M A.Removal of Organophosphorus Pesticides from Water by Electrogenerated Fenton's Reagent[J]. Environ Chem Lett,2003,1(3):165-168.
[8]	Naushad M,Alothman Z,Khan M,et al. Equilibrium, Kinetics and Thermodynamic Studies for the Removal of Organophosphorus Pesticide Using Amberlyst-15 Resin:Quantitative Analysis by Liquid Chromatography-Mass Spectrometry[J]. J Ind Eng Chem,2014,20(6):4393-4400.
[9]	Cycoń M,zmijowska A,Wójcik M,et al.Biodegradation and Bioremediation Potential of Diazinon-degrading Serratia marcescens to Remove Other Organophosphorus Pesticides from Soils[J]. J Environ Manage,2013,117:7-16.
[10]	Wei W,Du J J,Li J,et al. Construction of Robust Enzyme Nanocapsules for Effective Organophosphate Decontamination, Detoxification, and Protection[J]. Adv Mater,2013,25(15):2212-2218.
[11]	Ahmad A,Tan L,Shukor S A.Dimethoate and Atrazine Retention from Aqueous Solution by Nanofiltration Membranes[J]. J Hazard Mater,2008,151(1):71-77.
[12]	Badawy M I,Ghaly M Y,Gad-Allah T A. Advanced Oxidation Processes for the Removal of Organophosphorus Pesticides from Wastewater[J]. Desalination,2006,194(1/2/3):166-175.
[13]	Tolosa I,Readman J W,Mee L D.Comparison of the Performance of Solid-phase Extraction Techniques in Recovering Organophosphorus and Organochlorine Compounds from Water[J]. J Chromatogr A,1996,725(1):93-106.
[14]	Aksu Z.Determination of the Equilibrium, Kinetic and Thermodynamic Parameters of the Batch Biosorption of Nickel(Ⅱ) Ions onto Chlorella vulgaris[J]. Process Biochem,2002,38(1):89-99.
[15]	Li Y H,Di Z C,Ding J,et al. Adsorption Thermodynamic, Kinetic and Desorption Studies of Pb2+ on Carbon Nanotubes[J]. Water Res,2005,39(4):605-609.
[16]	Halsey G D.The Role of Surface Heterogeneity in Adsorption[J]. Adv Catal,1952,4:259-269.
[17]	Erdem E,Çölgeçen G,Donat R.The Removal of Textile Dyes by Diatomite Earth[J]. J Colloid Interface Sci,2005,282(2):314-319.
[18]	Zhu L L,Deng Y F,Zhang J P,et al. Adsorption of Phenol from Water by N-Butylimidazolium Functionalized Strongly Basic Anion Exchange Resin[J]. J Colloid Interface Sci,2011,364(2):462-468.
[19]	Onganer Y,Temur Ç.Adsorption Dynamics of Fe(Ⅲ) from Aqueous Solutions onto Activated Carbon[J]. J Colloid Interface Sci,1998,205(2):241-244.
[20]	Ho Y S,McKay G. Pseudo-second Order Model for Sorption Processes[J]. Process Biochem,1999,34(5):451-465.
[21]	Basha S,Murthy Z,Jha B.Sorption of Hg(Ⅱ) onto Carica papaya:Experimental Studies and Design of Batch Sorber[J]. Chem Eng J,2009,147(2):226-234.
[22]	Djeribi R,Hamdaoui O.Sorption of Copper(Ⅱ) from Aqueous Solutions by Cedar Sawdust and Crushed Brick[J]. Desalination,2008,225(1/2/3):95-112.
[23]	Boyd G,Adamson A,Myers Jr L.The Exchange Adsorption of Ions from Aqueous Solutions by Organic Zeolites.Ⅱ.Kinetics[J]. J Am Chem Soc,1947,69(11):2836-2848.
[24]	Mohan D,Singh K P.Single-and Multi-component Adsorption of Cadmium and Zinc Using Activated Carbon Derived from Bagasse—An Agricultural Waste[J]. Water Res,2002,36(9):2304-2318.

Recovery of Organphosphorus Extractants from Water by Anion Exchange Resin

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