Synthesis of Terpolymers Derived from CO2, Propylene Oxide and Tetrachlorophthalic Anhydride Using Double Metal Cyanide Catalysts by Ball Milling

doi:10.11944/j.issn.1000-0518.2018.06.170211

Chinese Journal of Applied Chemistry ›› 2018, Vol. 35 ›› Issue (6): 659-664.DOI: 10.11944/j.issn.1000-0518.2018.06.170211

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Synthesis of Terpolymers Derived from CO₂, Propylene Oxide and Tetrachlorophthalic Anhydride Using Double Metal Cyanide Catalysts by Ball Milling

SHI Jia,SONG Huangwang,ZHU Qidong,LIN Qiang(),ZHU Linhua(),LIU Yinghao,ZHONG Wanlin

College of Chemistry and Chemical Engineering,Hainan Normal University,Haikou 571158,China

Received:2017-06-16 Accepted:2017-09-01 Published:2018-06-01 Online:2018-05-28
Contact: LIN Qiang,ZHU Linhua
Supported by:
Supported by the Scientific and Technical Personnel Services Business Projects(No.2009GJE20014), the Natural Science Foundation of Hainan Province(No.217108)

Abstract

Abstract:

The addition of co-complexing agent is beneficial to improve the catalytic activity of the double metal cyanide(DMC) catalyst. In this paper poly(propylene carbonate tetrachlorophthalic phthalate)(PPCPA) terpolymers were successfully synthesized from carbon dioxide, propylene oxide and tetrachlorophthalic anhydride catalyzed by ball milling synthesized Zn-Co DMC catalysts. The properties and structures of Zn-Co DMC catalysts and the resulting terpolymers were characterized by Fourier transform infrared spectroscopy(FTIR), scanning electron microscope(SEM), X-ray diffraction(XRD), gel permeation chromatography(GPC) and thermogravimetric analysis(TG). The results show that the turnover number of Zn-Co DMC catalysts is up to 25.67~141.80, and the number-average relative molecular mass of PPCPA is up to 2.21×10³~3.15×10³ with a narrow polydispersity index of 1.04~1.24. Compared with polypropylene carbonate(PPC), PPCPA shows a higher thermal stability, and the thermal decomposition temperature of PPCPA is increased by 129.8 ℃.

Key words: ball milling, Zn-Co double metal cyanide catalysts, co-complexing agents, tetrachlorophthalic anhydride, terpolymerization

SHI Jia,SONG Huangwang,ZHU Qidong,LIN Qiang,ZHU Linhua,LIU Yinghao,ZHONG Wanlin. Synthesis of Terpolymers Derived from CO₂, Propylene Oxide and Tetrachlorophthalic Anhydride Using Double Metal Cyanide Catalysts by Ball Milling[J]. Chinese Journal of Applied Chemistry, 2018, 35(6): 659-664.

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Synthesis of Terpolymers Derived from CO₂, Propylene Oxide and Tetrachlorophthalic Anhydride Using Double Metal Cyanide Catalysts by Ball Milling

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