Rational Design of Zeolitic Tetrazolate Frameworks with Carboxylate Ligands for Rapid Accumulation of Iodine

doi:10.11944/j.issn.1000-0518.2017.09.170183

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (9): 1072-1078.DOI: 10.11944/j.issn.1000-0518.2017.09.170183

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Rational Design of Zeolitic Tetrazolate Frameworks with Carboxylate Ligands for Rapid Accumulation of Iodine

JIANG Zhiqiang^a^b,WANG Fei^a,ZHANG Jian^a^*()

^aState Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,the Chinese Academy of Sciences,Fuzhou 350002,China
^bPanzhihua Key Laboratory of Chemical Resource Engineering,Panzhihua University,Panzhihua,Sichuan 617000,China

Received:2017-05-27 Accepted:2017-07-05 Published:2017-08-31 Online:2017-08-31
Contact: ZHANG Jian
Supported by:
Supported by the National Natural Science Foundation of China(No.21573236), the Open Foundation of State Key Laboratory of Structural Chemistry(No.20150012), the Science and Technology Planning Project in Sichuan Province(No.2014GZ0030, No.2015RZ0029), the Science and Technology Planning Project in Panzhihua City(No.2014CY-G-24, No.2016CY-G-4)

Abstract

Abstract:

Zeolitic metal-organic frameworks(MOFs) with high porosity, controlled pore size, regular pore shape, high thermal and chemical stability have been extensively studied and display potential applications in the field of rapid accumulation of iodine. Here, through simulating the structure of zeolite, two tetrahedral tetrazolate frameworks(TTF-8 and TTF-9) were successfully assembled via using thiophene-2,5-dicarboxylate and 4,4'-oxybisbenzoic acid as an auxiliary ligand, respectively. The results of single-crystal X-ray diffraction measurement show that TTF-8 crystallizes in a tetragonal space group of P4₂mc, while TTF-9 exhibits a monoclinic space group of P2₁/c. Remarkably, although TTF-8 and TTF-9 exhibit the same BCT topology, their frameworks and pore structures are entirely different. Two TTFs materials display outstanding performance on rapidly enriching iodine.

Key words: zeolitic tetrazolate frameworks, assembly strategy, absorbing iodine

JIANG Zhiqiang, WANG Fei, ZHANG Jian. Rational Design of Zeolitic Tetrazolate Frameworks with Carboxylate Ligands for Rapid Accumulation of Iodine[J]. Chinese Journal of Applied Chemistry, 2017, 34(9): 1072-1078.

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Rational Design of Zeolitic Tetrazolate Frameworks with Carboxylate Ligands for Rapid Accumulation of Iodine

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