Microcalorimetric Study of Micrococcus Luteus Inhibition by Rare Earth Complexes with Carboxylate Ligand

doi:10.11944/j.issn.1000-0518.2017.05.160296

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (5): 582-589.DOI: 10.11944/j.issn.1000-0518.2017.05.160296

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Microcalorimetric Study of Micrococcus Luteus Inhibition by Rare Earth Complexes with Carboxylate Ligand

CEN Peipei^a,HE Yanping^b,LI Feifei^a,CAO Liang^a,CHEN Xiaoyan^a,SONG Weiming^a^*()

^aSchool of Chemistry and Chemical Engineering,Ningxia University,Yinchuan 750021,China
^bDrug Manufacturing Center,General Hospital of Ningxia Medical University,Yinchuan 750004,China

Received:2016-07-15 Accepted:2016-10-12 Published:2017-05-02 Online:2017-05-02
Contact: SONG Weiming
Supported by:
Supported by the National Natural Science Foundation of China(No.21463020), Natural Science Foundation of Ningxia Province(No.NZ16035), Foundation for Fostering Outstanding Young Teachers of Ningxia Higher Education Institutions of China(No.NGY2016063), the Science Research Projects of Ningxia Higher Education Institutions of China(Grant Nos.NGY2015026)

Abstract

Abstract:

Four isostructural rare earth complexes, namely [Re₂(oba)₃(H₂O)₅]·H₂O[Re=La(1), Ce(2), Sm(3), Er(4), H₂oba=4,4'-oxybisbenzoic acid], have been synthesized under solvothermal conditions and characterized by elemental analysis, infrared(IR) spectrometry, and powder X-ray diffraction. Thermogravimetric analysis demonstrates that these complexes possess good thermostability. Micrococcus luteus inhibition by these complexes have been real-time detected by means of microcalorimetry. The growth rate constant k, maximum power P_max, passage time t_G and inhibitive ratio I, respectively, have been obtained. Experimental results indicate that the title complexes present effective inhibition on Micrococcus luteus, and the order is listed as follows:[Er₂(oba)₃(H₂O)₅]·H₂O(4)>[Sm₂(oba)₃(H₂O)₅]·H₂O(3)>[Ce₂(oba)₃(H₂O)₅]·H₂O(2)>[La₂(oba)₃(H₂O)₅]·H₂O(1).

Key words: rare earth carboxylic complexes, microcalorimetry, Micrococcus luteus, thermodynamics

CEN Peipei, HE Yanping, LI Feifei, CAO Liang, CHEN Xiaoyan, SONG Weiming. Microcalorimetric Study of Micrococcus Luteus Inhibition by Rare Earth Complexes with Carboxylate Ligand[J]. Chinese Journal of Applied Chemistry, 2017, 34(5): 582-589.

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Microcalorimetric Study of Micrococcus Luteus Inhibition by Rare Earth Complexes with Carboxylate Ligand

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