Synthesis and Properties of Polyesters Containing 8-Hydroxyquinoline Side Groups and Their Zn(Ⅱ), Al(Ⅲ) Complexes

doi:10.11944/j.issn.1000-0518.2017.03.160304

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (3): 338-344.DOI: 10.11944/j.issn.1000-0518.2017.03.160304

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Synthesis and Properties of Polyesters Containing 8-Hydroxyquinoline Side Groups and Their Zn(Ⅱ), Al(Ⅲ) Complexes

WU Yan,GUO Zhaonan,LYU Chengwei,YU Shijun()

School of Chemistry and Chemical Engineering,Liaoning Normal University,Dalian,Liaoning 116029,China

Received:2016-07-28 Accepted:2016-10-08 Published:2017-02-27 Online:2017-02-27
Contact: YU Shijun
Supported by:
Supported by the National Natural Science Foundation of China(No.21403100), the Science and Technology Research Project of the Department of Education of Liaoning Province(No.L2012383)

Abstract

Abstract:

Two kinds of novel polyesters containing 8-hydroxyquinoline side groups(P5, P6) were synthesized by multistep reactions. Subsequently, polyesters P5 and P6 reacted with zinc acetate and aluminum chloride to get zinc complexes(P5-Zn, P6-Zn) and aluminum complexes(P5-Al, P6-Al). The structures and properties of polyesters and metal complexes were characterized by elemental analysis, IR, UV-Vis, ¹H NMR, GPC, TG and fluorescence spectroscopy. Polyesters P5 and P6 can be easily dissolved in many solvents such as tetrahydrofurane(THF), N,N-dimethyl formamide(DMF), N,N-dimethyl acetamide(DMAC), dimethylsulfoxide(DMSO), and N-methyl pyrrolidone(NMP) at room temperature. Complexes P5-Zn, P6-Zn, P5-Al and P6-Al can be partially dissolved in DMF, DMAc, DMSO and NMP. The mass mean relative molecular mass(M_w) and polydispersity index(PDI) of P5 and P6 are 41200, 54200 and 1.50, 1.40, respectively. The 5% mass loss temperatures of P5, P6, P5-Zn, P6-Zn, P5-Al and P6-Al are 261.4, 291.1, 307.7, 306.2, 286.3 and 297.8 ℃, respectively. Fluorescence emission peaks of P5 and P6 in DMF solution appear at 432 and 429 nm, emitting weak purple light. Fluorescence emission peaks of P5-Zn, P6-Zn, P5-Al and P6-Al in solid state emerge at 550, 556, 531, 535 nm, emitting strong green light, which are all red-shifted to some extent, compared with their emission peaks in DMF solution located at 540, 537, 517 and 522 nm.

Key words: 8-hydroxyquinoline, polyester, zinc complex, aluminum complex

WU Yan, GUO Zhaonan, LYU Chengwei, YU Shijun. Synthesis and Properties of Polyesters Containing 8-Hydroxyquinoline Side Groups and Their Zn(Ⅱ), Al(Ⅲ) Complexes[J]. Chinese Journal of Applied Chemistry, 2017, 34(3): 338-344.

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Synthesis and Properties of Polyesters Containing 8-Hydroxyquinoline Side Groups and Their Zn(Ⅱ), Al(Ⅲ) Complexes

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