Synthesis and Characterization of Magnetic and Fluorescent Bifunctional Fe3O4@SiO2@ZrO2:Tb3+ Spherical Nanocomposites

doi:10.11944/j.issn.1000-0518.2016.08.150396

Chinese Journal of Applied Chemistry ›› 2016, Vol. 33 ›› Issue (8): 968-976.DOI: 10.11944/j.issn.1000-0518.2016.08.150396

• Full Papers • Previous Articles

Synthesis and Characterization of Magnetic and Fluorescent Bifunctional Fe₃O₄@SiO₂@ZrO₂:Tb³⁺ Spherical Nanocomposites

YUAN Senwen^a^b,ZHAO Lang^b^*(),LI Hongtao^a^*()

^a School of Chemistry and Life Science,Changchun University of Technology,Changchun 130012,China
^b State Key Laboratory of Rare Earth Resource Utilization,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China

Received:2015-11-10 Accepted:2016-01-21 Published:2016-07-21 Online:2016-07-21
Contact: ZHAO Lang,LI Hongtao
Supported by:
Supported by the National Natural Science Foundation of China(No.21201160), Opening Fund of Key Laboratory of Functional Inorganic Material Chemistry(Heilongjiang University), Ministry of Education

Abstract

Abstract:

New water-soluble magnetic and fluorescent Fe₃O₄@SiO₂@ZrO₂:Tb³⁺ nanocomposites(NCs) have been successfully synthesized through the in situ synthesized method. The morphology, size, phase, magnetic properties and fluorescent properties of as-synthesized nanoparticles(NPs) were well investigated by scanning electron microscopy(SEM), X-ray diffraction(XRD), Fourier transform infrared spectroscopy(FT-IR), magnetometer, and photoluminescence(PL) spectra. The magnetic and fluorescent NPs consist of silica-coated Fe₃O₄as the core and the ZrO₂:Tb³⁺ as the shell exhibit superparamagnetism with the saturation magnetization of 36 emu/g and fluorescence properties with four emission bands peaked at approximately 494 nm(⁵D₄→⁷F₆), 549 nm(⁵D₄→⁷F₅), 587 nm(⁵D₄→⁷F₄), and 625 nm(⁵D₄→⁷F₃) of Tb³⁺ ions. The bifunctional magnetic and fluorescence NCs will show potential applications in biomedical fields in the future.

Key words: water-soluble, bifunctional, magnetic and fluorescent

YUAN Senwen,ZHAO Lang,LI Hongtao. Synthesis and Characterization of Magnetic and Fluorescent Bifunctional Fe₃O₄@SiO₂@ZrO₂:Tb³⁺ Spherical Nanocomposites[J]. Chinese Journal of Applied Chemistry, 2016, 33(8): 968-976.

References

[1]	Gong X Q,Zhang Q,Cui Y,et al.A Facile Method to Prepare High-Performance Magnetic and Fluorescent Bifunctional Nanocomposites and Their Preliminary Application in Biomolecule Detection[J]. J Mater Chem B,2013,1(15):2098-2106.
[2]	Lu Y J,He B C,Shen J,et al.Multifunctional Magnetic and Fluorescent Core-Shell Nanoparticles for Bioimaging[J]. Nanoscale,2015,7(5):1606-1609.
[3]	Yu S,Gao X,Jing H,et al.Fabrication and Characterization of Novel Magnetic/Luminescent Multifunctional Nanocomposites for Controlled Drug Release[J]. Cryst Eng Comm,2014,16(29):6645-6653.
[4]	Hou Y,Yin Z,Xin H,et al.Fe3O4 Modified Up-Conversion Luminescent Nanocrystals for Biological Applications[J]. Chinese J Chem,2012,30(12):2774-2778.
[5]	Wang Z,Ma X,Zong S,et al.Preparation of a Magnetofluorescent Nano-Hermometer and Its Targeted Temperature Sensing Applications in Living Cells[J]. Talanta,2015,131:259-265.
[6]	Zhou X,Ma Q,Dong X,et al.Flexible Janus Nanofibers:A Feasible Route to Realize Simultaneously Tuned Magnetism and Enhanced Color-Tunable Luminescence Bifunctionality[J]. RSC Adv,2015,5(45):35948-35957.
[7]	Wang W,Zou M,Chen K. Novel Fe3O4@YPO4:Re(Re=Tb,Eu) Multifunctional Magnetic-Fluorescent Hybrid Spheres for Biomedical Applications[J]. Chem Commun,2010,46(28):5100-5102.
[8]	Yan K,Li H,Li P,et al.Self-assembled Magnetic Fluorescent Polymeric Micelles for Magnetic Resonance and Optical Imaging[J]. Biomaterials,2014,35(1):344-355.
[9]	Huang L,Zhang Y,Liu H,et al.Synthesis and Properties of Magnetic Fluorescent Bi-Functional Graphene Oxide-Based Nanocomposites[J]. New J Chem,2014,38(12):5817-5824.
[10]	Kacenka M,Kaman O,Kikerlová S,et al.Fluorescent Magnetic Nanoparticles for Cell Labeling:Flux Synthesis of Manganite Particles and Novel Functionalization of Silica Shell[J]. J Colloid Interface Sci,2015,447:97-106.
[11]	Shi D,Sadat M E,Dunn A W,et al.Photo-Fluorescent and Magnetic Properties of Iron Oxide Nanoparticles for Biomedical Applications[J]. Nanoscale,2015,7(18):8209-8232.
[12]	Hu Y,Qian H,Guo C,et al.Decoration of ZnO Nanocrystals on the Surface of Shuttle-Shaped Mn2O3 and Its Magnetic-Optical Properties[J]. Cryst Eng Comm,2010,12(10):2687-2690.
[13]	Ge J,Hu Y,Biasini M,et al.Superparamagnetic Magnetite Colloidal Nanocrystal Clusters[J]. Angew Chem Int Ed,2007,46(23):4342-4345.
[14]	Shen L H,Bao J F,Wang D,et al.One-Step Synthesis of Monodisperse, Water-Soluble Ultra-Small Fe3O4 Nanoparticles for Potential Bio-Application[J]. Nanoscale,2013,5(5):2133-2141.
[15]	Hwang D W,Song I C,Lee D S,et al.Smart Magnetic Fluorescent Nanoparticle Imaging Probes to Monitor MicroRNAs[J]. Small,2010,6(1):81-88.
[16]	Jing P,Wang Q,Liu B,et al.Controlled Fabrication of Bi-Functional Fe3O4@SiO2@Gd2O3:Yb,Er Nanoparticles and Their Magnetic, Up-Conversion Luminescent Properties[J]. RSC Adv,2014,4(84):44575-44582.
[17]	Tang H,Zhou C,Wu R,et al.The Enhanced Fluorescence Properties & Colloid Stability of Aqueous CdSe/ZnS QDs Modified with N-Alkylated Poly(ethyleneimine)[J]. New J Chem,2015,39(6):4334-4342.
[18]	Li C L,Huang B R,Chang J Y,et al.Bifunctional Superparamagnetic-Luminescent Core-Shell-Satellite Structured Microspheres:Preparation, Characterization, and Magnetodisplay Application[J]. J Mater Chem C,2015,3(18):4603-4615.
[19]	Lv X,Li Y,Yan T,et al.An Electrochemiluminescent Immunosensor Based on CdS-Fe3O4 Nanocomposite Electrodes for the Detection of Ochratoxin A[J]. New J Chem,2015,39(6):4259-4264.
[20]	Yen S K,Jańczewski D,Lakshmi J L,et al.Design and Synthesis of Polymer-Functionalized NIR Fluorescent Dyes-Magnetic Nanoparticles for Bioimaging[J]. ACS Nano,2013,7(8):6796-6805.
[21]	Zhang Y, Gong S W Y, Jin L, et al. Magnetic Nanocomposites of Fe3O4/SiO2-FITC with pH-Dependent Fluorescence Emission[J]. Chinese Chem Lett,2009,20(8):969-972.
[22]	Singh N S,Hrishikesh K,Lina P,et al.A Multifunctional Biphasic Suspension of Mesoporous Silica Encapsulated with YVO4:Eu3+ and Fe3O4 Nanoparticles:Synergistic Effect towards Cancer Therapy and Imaging[J]. Nanotechnology,2013,24(6):065101.
[23]	Zhou L,Gu Z,Liu X,et al.Size-Tunable Synthesis of Lanthanide-Doped Gd2O3 Nanoparticles and Their Applications for Optical and Magnetic Resonance Imaging[J]. J Mater Chem,2012,22(3):966-974.
[24]	Zhao P,Zhu Y,Yang X,et al.Facile Synthesis of Upconversion Luminescent Mesoporous Y2O3:Er Microspheres and Metal Enhancement Using Gold Nanoparticles[J]. RSC Adv,2012,2(28):10592-10597.
[25]	Zhai X,Liu S,Liu X,et al.Sub-10 nm BaYF5:Yb3+,Er3+ Core-Shell Nanoparticles with Intense 1.53 μm Fluorescence for Polymer-Based Waveguide Amplifiers[J]. J Mater Chem C,2013,1(7):1525-1530.
[26]	Chen F,Chen M,Yang C,et al.Terbium-Doped Gadolinium Oxide Nanoparticles Prepared by Laser Ablation in Liquid for Use as a Fluorescence and Magnetic Resonance Imaging Dual-Modal Contrast Agent[J]. Phys Chem Chem Phys,2015,17(2):1189-1196.
[27]	Duan N,Zhang H,Nie Y,et al.Fluorescence Resonance Energy Transfer-Based Aptamer Biosensors for Bisphenol A Using lanthanide-doped KGdF4 nanoparticles[J]. Anal Methods,2015,7(12):5186-5192.
[28]	Sato K,Abe H,Ohara S. Selective Growth of Monoclinic and Tetragonal Zirconia Nanocrystals[J]. J Am Chem Soc,2010,132(8):2538-2539.
[29]	Joo J,Yu T,Kim Y W,et al.Multigram Scale Synthesis and Characterization of Monodisperse Tetragonal Zirconia Nanocrystals[J]. J Am Chem Soc,2003,125(21):6553-6557.
[30]	Ninjbadgar T,Garnweitner G,Börger A,et al.Synthesis of Luminescent ZrO2:Eu3+ Nanoparticles and Their Holographic Sub-Micrometer Patterning in Polymer Composites[J]. Adv Funct Mater,2009,19(11):1819-1825.
[31]	Liu Y,Zhou S,Tu D,et al.Amine-Functionalized Lanthanide-Doped Zirconia Nanoparticles: Optical Spectroscopy, Time-Resolved Fluorescence Resonance Energy Transfer Biodetection, and Targeted Imaging[J]. J Am Chem Soc,2012,134(36):15083-15090.
[32]	Tong L,Shi J,Liu D,et al.Luminescent and Magnetic Properties of Fe3O4@SiO2@Y2O3:Eu3+ Composites with Core Shell Structure[J]. J Phys Chem C,2012,116(12):7153-7157.
[33]	Yi D K,Lee S S,Papaefthymiou G C,et al.Nanoparticle Architectures Templated by SiO2/Fe2O3 Nanocomposites[J]. Chem Mater,2006,18(3):614-619.
[34]	Deng Y,Qi D,Deng C,et al.Superparamagnetic High-Magnetization Microspheres with an Fe3O4@SiO2 Core and Perpendicularly Aligned Mesoporous SiO2 Shell for Removal of Microcystins[J]. J Am Chem Soc,2008,130(1):28-29.
[35]	Sun P,Zhang H,Liu C,et al.Preparation and Characterization of Fe3O4/CdTe Magnetic/Fluorescent Nanocomposites and Their Applications in Immunolabeling and Fluorescent Imaging of Cancer Cells[J]. Langmuir,2010,26(2):1278-1284.
[36]	Qin S,Cai W,Tang X,et al.Sensitively Monitoring Photodegradation Process of Organic Dye Molecules by Surface-Enhanced Raman Spectroscopy Based on Fe3O4@SiO2@TiO2@Ag Particle[J]. Analyst,2014,139(21):5509-5515.

Synthesis and Characterization of Magnetic and Fluorescent Bifunctional Fe₃O₄@SiO₂@ZrO₂:Tb³⁺ Spherical Nanocomposites

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 6

Recommended Articles

Metrics

Comments

[1]	YUAN Senwen, ZHAO Lang, LI Hongtao. Synthesis and Characterization of Magnetic and Fluorescent Bifunctional Fe₃O₄@SiO₂@ZrO₂:Tb³⁺ Spherical Nanocomposites [J]. Chinese Journal of Applied Chemistry, 2016, 33(8): 0-0.
[2]	Ying Zongrong, Wu Dacheng. Structure and Properties of Water-Soluble Polyester [J]. Chinese Journal of Applied Chemistry, 1998, 0(5): 59-61.
[3]	Zhang Liming, Li Zhuomei. Water-Soluble Amphoteric Cellulose Derivatives──Ⅰ.Quaternary Ammonium Cationization of Carboxymethylcellulose [J]. Chinese Journal of Applied Chemistry, 1998, 0(4): 5-8.
[4]	Sun Dayong, Liu Ziyang, Guo Xinghua, Liu Shuying. Preparation and Bioactivity of Water-Soluble C₆₀ Derivatives [J]. Chinese Journal of Applied Chemistry, 1996, 0(4): 1-4.
[5]	Wang Junzhen, Gu Fengcai, Yan Xiuru, Wang Jianping, Zeng Shulan. Photodegtgradation of Water-Soluble Dyes in PbTiO₃ System [J]. Chinese Journal of Applied Chemistry, 1995, 0(6): 29-32.
[6]	Bo Shuqin, Yang Guojun, Pei Yihui, Cheng Rongshi. Determination of Specific Refractive Index Increments of Water Soluble Polymers by Quantitative Size Exclution Chromatography [J]. Chinese Journal of Applied Chemistry, 1995, 0(4): 11-17.