Synthesis and Application of Novel Tripod-type Benzimidazolium Compounds

doi:10.11944/j.issn.1000-0518.2015.08.140402

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (8): 873-883.DOI: 10.11944/j.issn.1000-0518.2015.08.140402

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Synthesis and Application of Novel Tripod-type Benzimidazolium Compounds

ZHANG Chenglu(),SUN Lijie,SONG Buer,GUO Yang,ZHAO Baocheng,TANG Jie,XI Huan

College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, China

Received:2014-11-19 Accepted:2015-05-05 Published:2015-08-08 Online:2015-08-08
Contact: ZHANG Chenglu
Supported by:
Supported by Science and Technology Project of the Liaoning Province Education Department(No.2009A426)

Abstract

Abstract:

Fifteen new tripod type benzimidazolium salts(3a~3o) were synthesized and characterized by IR, NMR and HRMS. The plant growth regulating activities of compound 3 were evaluated. Compounds 3a, 3c, 3f, 3g, 3h, 3i and 3j exhibit excellent cytokinesis activities up to 88.3% at the concentration of 10 mg/L which are higher than that of the reference triadimefon(50.2%), but their auxin activities are not obviously effective. Nearly all the target compounds have excellent herbicidal activity, while compound 3i is the best with 95.6%. The fluorescent identification of the four representative target molecules on six important anions was explored by fluorescence spectrum. The target compounds can be used as fluorescence probe for I^- identification.

Key words: benzimidazole, biological activity, plant growth regulator, anionic identification

CLC Number:

ZHANG Chenglu, SUN Lijie, SONG Buer, GUO Yang, ZHAO Baocheng, TANG Jie, XI Huan. Synthesis and Application of Novel Tripod-type Benzimidazolium Compounds[J]. Chinese Journal of Applied Chemistry, 2015, 32(8): 873-883.

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Synthesis and Application of Novel Tripod-type Benzimidazolium Compounds

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