Research Development of Cerium-Zinc Flow Battery

doi:10.3724/SP.J.1095.2013.20587

Chinese Journal of Applied Chemistry

• Review • Previous Articles Next Articles

Research Development of Cerium-Zinc Flow Battery

JIN Rongrong^1,2, MA Liqun¹, YIN Dongming², WANG Limin^2,3*

(1.College of Materials Science and Engineering,Nanjing University of Technology，Nanjing 210009,China;
2.State Key Laboratory of Rare Earth Resource Utilization,Changchun Institute of Applied Chemistry,
Chinese Academy of Sciences,Changchun 130022,China;
3.Changzhou Institute of Energy Storage Materials & Devices,Changzhou 213000,China)

Received:2012-12-13 Revised:2013-01-11 Published:2013-08-10 Online:2013-08-10
Contact: Wang limin

Abstract

Abstract: Cerium-Zinc redox flow battery has a significant high voltage compared with other redox flow batteries. The potential utilization of cerium-zinc redox flow battery is most likely to occur in energy storage system due to the abundant resources of raw materials and cost-efficient products. This review summarized the recent research and development of cerium-zinc flow batteries, especially for electrolytes of batteries, and analyzes further development prospective of ceriumzinc flow batteries.

Key words: Cerium-Zinc flow battery, electrolytes, electrode materials, research development.

CLC Number:

O614

JIN Rongrong1,2, MA Liqun1, YIN Dongming2, WANG Limin2,3*. Research Development of Cerium-Zinc Flow Battery[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2013.20587.

References

[1] N R C. Committee for the National Academies Summit on America′s Energy Future(2008):Summary of a Meeting[C]. Washington:National Academies Press,DC.

[2] Thaller L H. Electrically Rechargeable Redox Flow Cells[A]. San Francisco,USA:SAE Preprints,749142,1974:924.

[3] Thaller L H. Electrically Rechargeable Redox Flow Cell:US 3996064[P],1974-09-24.

[4] Kondo S,Misaki H,Suzuki S. Development of Advanced Battery Electric Energy Storage System for Electric Utility Load Leveling[A]. Proceedings of the Intersociety Energy Conversion Engineering Conference[C]. Miami Beach，FL,USA:SAE(P2164),Warrendale,PA,USA，1985.11.

[5] Rychcik M,Skyllas K M. Characteristics of a New all Vanadium Redox Flow Battery[J]. J Power Sources,1988,22(1):59-67.

[6] Clarke R L,Dougherty B,Harrison S,et al.Cerium Batteries:US,7625663 B2[P],2004-10-14.

[7] Weber A Z,Mench M M,Meyers J P,et al. Redox Flow Batteries:a Review[J]. J Appl Electrochem,2011,41:1137-1164.

[8] Randle T H,Kuhn A T. The Influence of Platinum(phase) Oxide on the Electrode Kinetics of the Manganese(Ⅲ)/Manganese(Ⅱ) and Cerium(Ⅳ)/Cerium(Ⅲ) Redox Couples in Sulfuric Acid [J]. Electrochim Acta,1986,31(7):739-744.

[9] Vijayabarathi T,Velayutham D,Noel M. Influence of Aromatic Reactants and Products Involved in the Two Stage Electrochemical Oxidation on the Voltammetric Behaviour of Ce(Ⅳ)/Ce(Ⅲ) Redox Couple[J]. J Appl Electrochem,2001,31:979-986.

[10] XIA Xi,LIU Hongtao,LIU Yang.Studies on Ce4+/Ce3+ Redox System Using Linear Polarization and Ac Impedance Techniques[J]. Acta Chim Sin,2002,60(9):1630-1636(in Chinese).

夏熙,刘洪涛,刘洋. Ce4+/Ce3+氧化还原体系线性极化与交流阻抗研究[J]. 化学学报,2002,60(9):1630-1636.

[11] Paulenov A,Creager S E,Navratil J D,et al. Redox Potentials and Kinetics of the Ce3+/Ce4+ Redox Reaction and Solubility of Cerium Sulfates in Sulfuric Acid Solutions[J]. J Power Sources,2002,109:431-438.

[12] Fang B,Iwasa S,Wei Y,et al. A Study of the Ce(Ⅲ)/Ce(Ⅳ) Redox Couple for Redox Flow Battery Application[J]. Electrochim Acta,2002,47:3971-3976.

[13] Liu Y,Xia X,Liu H. Studies on Cerium(Ce4+/Ce3+)-Vanadium(V2+/V3+) Redox Cell:Cyclic Voltammogram Response of Ce4+/Ce3+ Redox Couple in H2SO4[J]. J Power Sources,2004,130:299-305.

[14] Wei Y,Fang B,Arai T,et al. Electrolytic Oxidation of Ce(Ⅲ) in Nitric Acid and Sulfuric Acid Media Using a Flow Type Cell[J]. J Appl Electrochem,2005,35:561-566.

[15] Raju T,Ahmed Basha C. Electrochemical Cell Design and Development for Mediated Electrochemical Oxidation-Ce(Ⅲ)/Ce(Ⅳ) System[J]. Chem Eng J,2005,114:55-65.

[16] Trinidad P,Ponce-de-Leon C,Walsh F C. The Use of Electrolyte Redox Potential to Monitor the Ce(Ⅳ)/Ce(Ⅲ) Couple[J]. J Environ Manage,2008,88:1417-1425.

[17] CHEN Yunyang,ZHOU Debi,WEN Meisheng,et al. Reduction Kinetic of Ce(Ⅳ)/Ce(Ⅲ) Couple in Methanesulfonic Acid[J]. J Chinese Soc Rare Earths,2010,28(6):665-670(in Chinese).

陈云扬,周德璧,温美盛,等. Ce(Ⅳ)/Ce(Ⅲ)电对在甲基磺酸体系中还原动力学的研究[J]. 中国稀土学报,2010,28(6):665-670.

[18] Modiba P,Crouch A M. Electrochemical Study of Cerium(Ⅳ) in the Presence of Ethylenediaminetetraacetic Acid(EDTA) and Diethylenetriaminepentaacetate(DTPA) Ligands [J]. J Appl Electrochem,2008,38:1293-1299.

[19] Leung P K,Ponce-de-Leon C，Low C T J,et al. Charaterization of a Zinc-Cerium Flow Battery[J]. J Power Sources,2011,196:5174-5185.

[20] Leung P K，Ponce-de-Leon C,Walsh F C. An Undivided Zinc-Cerium Redox Flow Battery Operating at Room Temperature(295 K)[J]. Electrochem Commun,2011,13:770-773.

[21] Leung P K,Ponce-de-Leon C,Low C T J,et al. Zinc Deposition and Dissolution in Methanesulfonic Acid onto a Carbon Composite Electrode as the Negative Electrode Reaction in a Hybrid Redox Flow Battery[J]. Electrochim Acta,2011,56:6536-6546.

[22] Xie Z P,Xiong F J,Zhou D B. Study of the Ce3+/Ce4+ Redox Couple in Mixed-Acid Media (CH3SO3H and H2SO4) for Redox Flow Battery Application[J]. Energy Fuel,2011,25:2399-2404.

[23] Modiba P，Matoetoe M，Crouch A M. Electrochemical Impedance Spectroscopy Study of Ce(Ⅳ) with Aminopolycarboxylate Ligands for Redox Flow Batteries Applications[J]. J Power Sources,2012,205:1-9.

[24] Xiong F J,Zhou D B,Xie Z P,et al. A Study of the Ce3+/Ce4+ Redox Couple in Sulfamic Acid for Redox Battery Application[J]. Appl Energy,2012,99:291-296.

[25] Leung P K,Ponce-de-Leon C,Walsh F C. The Influence of Operational Parameters on the Performance of an Undivided Zinc-Cerium Flow Battery[J]. Electrochim Acta,2012,80:7-14.

[26] XIA Xi,ZHANG Xiaogang. Inhibition for Zinc Anode in Zinc/MnO2 Batteries(Ⅰ)[J]. Battery,1995,25(1):31-33(in Chinese).

夏熙，张校刚. 锌锰电池中锌阳极的缓蚀(上)[J]. 电池，1995，25(1):31-33.

Research Development of Cerium-Zinc Flow Battery

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 5

Recommended Articles

Metrics

Comments

[1]	ZHAO Liping, TAO Keyu, WANG Hongyu, QI Li. Sodium Titanate Nanotube-Carbon Composite as Negative Electrode Materials for Na-Ion Supercapattery [J]. Chinese Journal of Applied Chemistry, 2018, 35(10): 1264-1270.
[2]	ZHAO Liping, CAI Xingnan, WANG Hongyu, QI Li. Molybdenum Trioxide:A New Type Negative Electrode Material for Electric Energy Storage Devices Using Na⁺-based Organic Electrolytes [J]. Chinese Journal of Applied Chemistry, 2017, 34(3): 262-268.
[3]	ZHAO Liping, CAI Xingnan, WANG Hongyu, QI Li. Molybdenum Trioxide:A New Type Negative Electrode Material for Electric Energy Storage Devices Using Na⁺-based Organic Electrolytes [J]. Chinese Journal of Applied Chemistry, 2017, 34(3): 0-0.
[4]	LIANG Xitong,PAN Wei,CHEN Kunfeng,XUE Dongfeng. Advance in Research and Development of Novel Supercapacitors [J]. Chinese Journal of Applied Chemistry, 2016, 33(8): 867-875.
[5]	LUO Heming*, YANG Peng, ZHAO Xia, ZHANG Jianqiang. Supercapacitors Prepared with Coke Powder Activated Carbons/Al-Substituted Ni(OH)2 Composite Electrode Materials [J]. Chinese Journal of Applied Chemistry, 2013, 30(01): 99-106.