Nonisothermal Decomposition Kinetics and Thermal Safety of Ag2(BTATz)·2H2O（BTATz=3,6-Bis(1-H-1,2,3,4-tetrazole-5-amino)-1,2,4,5-tetrazine）

doi:10.3724/SP.J.1095.2013.20555

Chinese Journal of Applied Chemistry

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Nonisothermal Decomposition Kinetics and Thermal Safety of Ag2(BTATz)·2H2O（BTATz=3,6-Bis(1-H-1,2,3,4-tetrazole-5-amino)-1,2,4,5-tetrazine）

REN Yinghui^1,2*, LI Wen², ZHANG Xianbo², ZHAO Fengqi¹, YI Jianhua¹, MA Haixia², XU Kangzhen², SONG Jirong^2,3

(1.Science and Technology on Combustion and Explosion Laboratory,Xi′an Modern Chemistry Research Institute,Xi′an 710065,China;
2.School of Chemical Engineering,Shaanxi Key Laboratory of Physico-inorganic Chemistry,Northwest University,Xi′an ,710069,China;
3.Conservation Technology Department,The Palace Museum,Beijing 100009,China)

Received:2012-11-29 Revised:2012-12-18 Published:2013-09-10 Online:2013-09-10

Abstract

Abstract: The silver salt of 3,6-bis(1-H-1,2,3,4-tetrazole-5-amino)-1,2,4,5-tetrazine(BTATz)(Ag2(BTATz)·2H2O) was synthesized by two steps, and its structure was characterized by elemental analysis, X-ray fluorescence diffraction and FT-IR spectra. The thermal behavior of the compound was studied under non-isothermal conditions using DSC and TGDTG methods, the result indicated that the thermal decomposition comprises of one endothermic and two exothermic stages, the nonisothermal decomposition reaction kinetics equation of the main exothermic stage can be expressed as:dα/dt=1014.29×{3(1-α)[-ln (1-α)]1/4/4}exp(-2.10×104/T). The values of the self-accelerating decomposition temperature(TSADT), critical temperatures of thermal explosion(Tb), thermal ignition temperature(TTIT) and the adiabatic time-to-explosion(tTIAD) for the compound were calculated as 517.10 K, 580.12 K, 531.00 K and 90.32 s, respectively. In addition, its thermal safety was evaluated.

Key words: bis(H-tetrazole-amino)-tetrazine, silver salt, thermal decomposition reaction kinetics, thermal safety

CLC Number:

O614.1

REN Yinghui1,2*, LI Wen2, ZHANG Xianbo2, ZHAO Fengqi1, YI Jianhua1, MA Haixia2, XU Kangzhen2, SONG Jirong2,3. Nonisothermal Decomposition Kinetics and Thermal Safety of Ag2(BTATz)·2H2O（BTATz=3,6-Bis(1-H-1,2,3,4-tetrazole-5-amino)-1,2,4,5-tetrazine）[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2013.20555.

References

[1] Hiskey M A,Chavez D. Propellant Containing 3,6-Bis(1H-1,2,3,4-tetrazol-5-ylamino)-1,2,4,5-tetrazine Tetrazine or Salts Thereof:US,6342589[P],2002.

[2] Hiskey M A,Chavez D E,Naud D. 3,6-Bis(1H-1,2,3,4-tetrazol-5-ylamino)-1,2,4,5-tetrazine or Salt Thereof:US,20030168140[P]，2003.

[3] Chavez D E,Hiskey M A,Naud D L. Tetrazine Explosives[J]. Propellants Explos Pyrotech，2004,29(4):209-215.

[4] Ali A N,Son S F,Hiskey M A,et al. Novel High Nitrogen Propellant Use in Solid Fuel Micropropulsion[J]. J Propulsion Power,2004,20(1):120-126.

[5] Yi J H,Zhao F Q,Wang B Z,et al. Thermal Behavior, Nonisothermal Decomposition Reaction Kinetics, Thermal Safety and Burning Rates of BTATz-CMDB Propellant [J]. J Hazard Mater,2010,181:432-439.

[6] YUE Shouti,YANG Shiqing. Synthesis and Properties of 3,6-Bis(1H-1,2,3,4-tetrazol-5-yl-amino)-1,2,4,5-tetrazine[J]. Chinese J Energ Mater,2004,12(3):155-157(in Chinese).

岳守体,阳世清. 3,6-双(1-氢-1,2,3,4-四唑-5-氨基)-1,2,4,5-四嗪的合成及其性能[J]. 含能材料,2004,12(3):155-157.

[7] Saikia A,Sivabalan R,Polke B G,et al. Synthesis and Characterization of 3,6-Bis(1H-1,2,3,4-tetrazol-5-ylamino)-1,2,4,5-tetrazine(BTATz):Novel High-nitrogen Content in Sensitive High Energy Material[J]. J Hazard Mater,2009,170:306-313.

[8] ZHANG Xinggao,ZHU Hui,YANG Shiqing,et al. Study on Thermal Decomposition Kinetics and Mechanism of Nitrogen-rich Compound BTATz[J]. Chinese J Propul Technol,2007,28(3):322-326(in Chinese).

张兴高,朱慧,阳世清,等. 富氮高能物质BTATz的热分解动力学和分解机理[J]. 推进技术，2007,28(3):322-326.

[9] LI Dan,REN Yinghui,ZHAO Fengqi,et al. Preparation, Crystal Structure, Specific Heat Capacity and Thermodynamic Properties of Diacetatobis(4-Amino-1,2,4-triazole) Zinc[J]. Chinese J Inorg Chem,2010,26(3):509-514(in Chinese).

李丹，任莹辉，赵凤起，等. 二乙酸·二(4-氨基-1,2,4-三唑)合锌(Ⅱ)配合物的制备、晶体结构、比热容及热力学性质[J]. 无机化学学报,2010,26（3）：509-514.

[10] WANG Bozhou,LAI Weipeng,LI Qian,et al. Synthesis, Characterization and Quantum Chemistry Study on 3,6-Bis(1H-1,2,3,4-tetrazol-5-yl-amino)-1,2,4,5-tetrazine[J]. Chinese J Org Chem,2008,28(3):422-427(in Chinese).

王伯周,来蔚鹏,刘愆,等. 3,6-双(1H-1,2,3,4-四唑-5-氨基)-1,2,4,5-四嗪的合成、表征及量子化学研究[J]. 有机化学学报，2008,28(3):422-427.

[11] Drake G,Hawkins T,Brand A ,et al. Energetic, Low-Melting Salts of Simple Heterocycles[J]. Propellants Explos Pyrotech,2003,28:174-180.

[12] TANG Zhan,REN Yan,YANG Li,et al. A New Way to Estimate the Thermal Decomposition Mechanism Function and Thermal Safety of RDX[J]. Chinese J Explos Propellants,2011,34(1):19-24(in Chinese).

汤崭，任雁，杨利,等. 一种判断RDX热分解机理函数与热安定性的方法[J]. 火炸药学报，2011,34(1):19-24.

[13] Gao H X,Ye C F,Gupta O D,et al. 2,4,5-Trinitroimidazole-Based Energetic Salts[J]. Chem Eur J,2007，13:3853-3860.

[14] ZHAO Fengqi,CHEN Pei,LI Shangwen,et al. Catalysis of Metallic Salts of Tetrazoles on Combustion of RDX-CMBD Propellant[J]. Acta Armamentarii,2004,25(1):30-33(in Chinese).

赵凤起，陈沛，李上文，等. 四唑类化合物的金属盐作为微烟推进剂燃烧催化剂的研究[J]. 兵工学报,2004，25(1):30-33.

[15] LUO Suoen,DU Baosheng,ZHANG Jian,et al. Applied Studies of New Energetic Catalysts in the Screw Extruded Energetic Propellant with Low Signature[J]. Chinese J Energ Mater,2001,9(3):130-132(in Chinese).

刘所恩，杜宝生，张建，等. 新型含能催化剂在低特征信号推进剂中的应用研究[J]. 含能材料，2001,9(3):130-132.

[16] ZHANG Guotao,ZHOU Zunning,ZHANG Tonglai,et al. Advances on Energetic Catalysts for Solid Propellant[J]. J Solid Rocket Technol,2011,34(3)：319-323(in Chinese).

张国涛，周遵宁，张同来，等. 固体推进剂含能催化剂研究进展[J]. 固体火箭技术，2011,34(3)：319-323.

[17] XU Kangzhen,SONG Jirong,ZHAO Fengqi,et al. Special Heat Capacity, Thermodynamic Properties and Adiabatic Time-to-Explosion of 1,1-Diamino-2,2-dinitroethylene[J]. Acta Chim Sin,2007,65(24):2827-2831(in Chinese).

徐抗震，宋纪蓉，赵凤起，等. 1,1-二氨基-2,2-二硝基乙烯的比热容、热力学性质及绝热至爆时间研究[J]. 化学学报,2007,65(24):2827-2831.

[18] REN Y H,YI J H,ZHAO F Q,et al. Synthesis, Decomposition Reaction Kinetics and Thermal Safety of Complex of Picric Acid[J]. Chinese J Explos Propellants,2010,33(3):19-24.

[19] HU Rongzu,GAO Shengli,ZHAO Fengqi,et al. Thermal Analysis Kinetics[M]. 2nd Ed. Beijing:Science Press,2008(in Chinese).

胡荣祖，高胜利，赵凤起，等. 热分析动力学[M]. 第2版. 北京：科学出版社，2008.

[20] Ozawa T B. A New Method of Analyzing Thermogravimetric Data[J]. Bull Chem Soc Jpn,1965,38:1881-1886.

[21] Kissinger H E. Reaction Kinetics in Differential Thermal analysis[J]. Anal Chem,1957,29:1702-1706.

[22] Zhao F Q,Hu R Z,Gao H X,et al. In:Bronna O E(Ed). New Developments in Hazardous Materials Research,New York:Nova Science Publishers Inc.,2006(Chapter 4).

Nonisothermal Decomposition Kinetics and Thermal Safety of Ag2(BTATz)·2H2O（BTATz=3,6-Bis(1-H-1,2,3,4-tetrazole-5-amino)-1,2,4,5-tetrazine）

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