Recycling of Carbon Fiber Reinforced Epoxy Resin Cured with Anhydride in Subcritical Water

doi:10.3724/SP.J.1095.2013.20326

Chinese Journal of Applied Chemistry

• Full Papers • Previous Articles Next Articles

Recycling of Carbon Fiber Reinforced Epoxy Resin Cured with Anhydride in Subcritical Water

WANG Yiming^1,2, LIU Jie^2*, WU Guangfeng¹, TANG Tao^2*

(1.School of Chemical Engineering,Changchun University of Technology,Changchun 130012;
2.State Key Laboratory of Polymer Physics and Chemistry,Changchun Institute of
Applied Chemistry,Chinese Academy of Sciences,Changchun 130022，China)

Received:2012-07-23 Revised:2012-09-13 Published:2013-06-10 Online:2013-06-10

Abstract

Abstract: Effect of additives on the decomposition behavior of the carbon fiber reinforced epoxy resin cured with anhydride in subcritical water was investigated. IR and GC-MS results show that the decomposition is ascribed to cleavage of ester bond. KOH and phenol does not exhibit the synergetic effect on the decomposition of anhydride cured epoxy resin. Alkaline conditions are found to be favorable to the cleavage of ester linkages. The carbon fiber reinforced methyl-tetrahydrophalic anhydride(MeTHPA) cured epoxy resin composite was totally decomposed with the addition of 0.2 mol/L KOH at 250 ℃ for 60 min. The tensile strength and morphology of the recycled carbon fibers are not influenced.

Key words: Carbon fiber, Epoxy resin, Chemical recycling, Sub-critical water

CLC Number:

O631

WANG Yiming1,2, LIU Jie2*, WU Guangfeng1, TANG Tao2*. Recycling of Carbon Fiber Reinforced Epoxy Resin Cured with Anhydride in Subcritical Water[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2013.20326.

[1]	Peng-Hui FAN, Jie LIU, Sheng-Hui LOU, Tao TANG. Research Progress on Synergists of Phosphorous Flame Retardants in Epoxy Resin [J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 653-665.
[2]	Chen-Chen ZHANG, Yu-Han LIU, Wen-Jie ZHAO, Bai-Jun LIU, Zhao-Yan SUN, Wan-Li LIU, Yan-Miao WANG, Wei HU. Preparation of Oxidized Organosolv Lignin⁃based Hydrophilic Sizing Agent and Its Application in Polypropylene [J]. Chinese Journal of Applied Chemistry, 2022, 39(12): 1854-1861.
[3]	Yong-Xin TANG, Li-Wu NIE. Effect of Epoxy Resin Content on the Performance of Luminous Resin Permeable Concrete [J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1665-1671.
[4]	YOU Geyun, FENG Bin, FAN Fangfang, YANG Changjie, LIANG Cong. Synthesis of Phosphorus-Nitrogen Synergistic Flame-Retardant Compounds with Imide Structure and Their Flame Retardant Effect on Epoxy Resin [J]. Chinese Journal of Applied Chemistry, 2020, 37(2): 144-154.
[5]	ZHANG Lu, WANG Haichang, LI Hua, WANG Huijun, HUI Linhai, PENG Meiling, ZHU Yutian. Progress of Recycling of Carbon Fiber/Resin Composites via Supercritical Fluid [J]. Chinese Journal of Applied Chemistry, 2020, 37(12): 1357-1363.
[6]	HOU Chengmin,LI Na,DONG Haitao,KOU Yanping. Preparation and Performance of Hybrid Superhydrophobic Materials from Fluorinated Epoxy Resin and Silica Nanoparticles [J]. Chinese Journal of Applied Chemistry, 2019, 36(7): 798-806.
[7]	ZHANG Lili, DING Huimin, ZHANG Jitang, XU Donghua, LI Zhifeng. Thermal Conductivity and Flame Retardancy of Carbon Nanotube Modified Epoxy Resin [J]. Chinese Journal of Applied Chemistry, 2017, 34(1): 46-53.
[8]	CHEN Mingfeng, LU Qingxin, LIU Canpei, LIN Jinhuo. Preparation and Thermal Property of Epoxy Resin Containing Aromatic Thiazole Groups [J]. Chinese Journal of Applied Chemistry, 2016, 33(3): 293-298.
[9]	ZHANG Huanhuan, XU Donghua, GUAN Dongbo, YAO Weiguo, SHI Tongfei. The Curing Process of Epoxy Resin Tooling Board for Slush Mold at Different Temperature [J]. Chinese Journal of Applied Chemistry, 2016, 33(3): 299-306.
[10]	HU Sanming, WEI Wei, YANG Tianbo, ZHENG Changmei, ZHENG Chunbai, DENG Pengyang. Properties of a New Type Heat-Resistant System of Epoxy Resin Cured at Room Temperature [J]. Chinese Journal of Applied Chemistry, 2016, 33(2): 175-180.
[11]	BAI Tian, GUO Anru, LI Ruijie, LIU Chang, XIAO Dehai. Effect of Diluent on Performances of High-Temperature Resistance Epoxy Resin [J]. Chinese Journal of Applied Chemistry, 2016, 33(12): 1401-1407.
[12]	MA Yuqin, ZHENG Changmei, YANG Tianbo, WEI Wei, LIU Meihua, ZHENG Chunbai, DENG Pengyang, GAO Ying. Reaction Characteristics of Epoxy Resins E-51 Cured by 1-Hexyl-3-Methyl Imidazole Iron Tetrachloride Salt [J]. Chinese Journal of Applied Chemistry, 2015, 32(6): 636-640.
[13]	LI Dan, SU Xiaosheng, ZHANG Chi. Application of Two-Dimensional Fourier Transform Infrared Correlation Spectroscopy on Dicyandiamide-Epoxy Network [J]. Chinese Journal of Applied Chemistry, 2015, 32(11): 1275-1282.
[14]	LIU Changling*, YANG Ning, ZHANG Zeyu. Preparation and Properties of Al₂O₃-Modified Epoxy Resin for Electronic Packaging [J]. Chinese Journal of Applied Chemistry, 2013, 30(12): 1417-1422.
[15]	ZHONG Yinhua, LUO Yan*, ZENG Jian, WEI Yinglin, WU Yehui. Epoxy Resin Toughened by Polyester Hot Melt Adhesive [J]. Chinese Journal of Applied Chemistry, 2012, 29(07): 745-750.

Recycling of Carbon Fiber Reinforced Epoxy Resin Cured with Anhydride in Subcritical Water

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments