Photosynthesis of Two Oxa Macrocyclic Compounds

doi:10.3724/SP.J.1095.2013.20250

Chinese Journal of Applied Chemistry

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Photosynthesis of Two Oxa Macrocyclic Compounds

WANG Weidong^1,4*, SUN Guofu², SHI Zhengchun^3,4, SHIMO Tetsuro⁴

(1.College of Chemical and Materials Engineering,Jilin Institute of Chemical Technology,Jilin 132022,China;
2.College of Chemical and Chemical Engineering,Xuchang University,Xuchang 461000,China;
3.Testing and Evaluation Center,Shenyang Research Institute of Chemical Industry，Shenyang 110071,China;
4.Faculty of Engineering,Kagoshima University,Kagoshima 890-0065,Japan)

Received:2012-06-06 Revised:2012-09-05 Published:2013-04-10 Online:2013-04-10

Abstract

Abstract: Two oxa macrocyclic compounds were synthesized via double [2+2] photocycloaddition reaction between 6,6′-dimethyl-4,4′-(trimethylenedioxy)-di-2-pyrone and ethylene glycol dimethacrylates(n=1~3) by photosensitizing effect of benzophenone in acetonitrile solution with yields of 14% and 7%, 20% and 11%, 31% and 14%, respectively. The structures of products were identified by FTIR, 1H NMR, MS and elemental analysis. The synthetic method has several advantages such as mild reaction conditions, simple operation and environmental friendliness.

Key words: di-pyrone, ethylene glycol dimethacrylate, cycloaddition, photsynthesis

CLC Number:

O621.3

WANG Weidong1,4*, SUN Guofu2, SHI Zhengchun3,4, SHIMO Tetsuro4. Photosynthesis of Two Oxa Macrocyclic Compounds[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2013.20250.

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Photosynthesis of Two Oxa Macrocyclic Compounds

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