Synthesis of 1,13-(Substituted methylene)-α-hydroxymethylcyclododecanol and Conformational Analysis of Possible Stereoisomers

Chinese Journal of Applied Chemistry ›› 1996, Vol. 0 ›› Issue (3): 25-29.

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Synthesis of 1,13-(Substituted methylene)-α-hydroxymethylcyclododecanol and Conformational Analysis of Possible Stereoisomers

Wang Daoquan, Chen Jinghong

Department of Applied Chemistry, Beijing Agricultural University, Beijing 100094

Received:1995-07-24 Revised:1995-12-29 Published:1996-06-10 Online:1996-06-10

Abstract

Abstract: Nine title compounds were synthesized from α-ethoxycarbonylcyclododecanone by reduction and condensation with aldehydes or ketones.Their structure was confirmed by IR, MS,¹H NMR and elemental analysis.Conformational analysis of possible stereoisomers was carried out and the result was supported by ¹H NMR.The pesticidal activities were exam-ined and some of them found to be effective in promoting the growth of plant.

Key words: (substituted methylene)hydroxymethylcyclododecanol, conformational analysis, plant growth regulator

Wang Daoquan, Chen Jinghong. Synthesis of 1,13-(Substituted methylene)-α-hydroxymethylcyclododecanol and Conformational Analysis of Possible Stereoisomers[J]. Chinese Journal of Applied Chemistry, 1996, 0(3): 25-29.

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Synthesis of 1,13-(Substituted methylene)-α-hydroxymethylcyclododecanol and Conformational Analysis of Possible Stereoisomers

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