Selective Oxidation of Propane over Bismuth Vanadomolybdate Catalysts

Chinese Journal of Applied Chemistry ›› 1996, Vol. 0 ›› Issue (2): 88-90.

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Selective Oxidation of Propane over Bismuth Vanadomolybdate Catalysts

Li Jing, Song Wei, Dou Bosheng

Changchun Institute of Aplied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received:1995-07-04 Revised:1995-11-06 Published:1996-04-10 Online:1996-04-10

Abstract

Abstract: We have investigated the catalytic properties of scheelite-type oxide Bi_1-x/3V_1-x-Mo_xO₄ in the selective oxidation of propane to acrolein.When x is 0.45, the catalyst Bi_0.85V_0.55Mo_0.45O₄ shows good catalytic effect; the selectivity for acrolein is 23% at 54% conversion of propane. Monovalent silver promoter markedly improves catalytic performance of the bismuth vanadomolybdate Bi_0.85V_0.55Mo_0.45O₄. Under the optimum reaction condition. the catalyst Ag_0.01Bi_0.85V_0.54Mo_0.45O₄ shows much better catalytic performance with the selectivity for acrolein being 32% at 52% conversion of propane.

Key words: propane, selective oxidation, bismuth vanadomolybdate, promoter, acrolein

Li Jing, Song Wei, Dou Bosheng. Selective Oxidation of Propane over Bismuth Vanadomolybdate Catalysts[J]. Chinese Journal of Applied Chemistry, 1996, 0(2): 88-90.

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Selective Oxidation of Propane over Bismuth Vanadomolybdate Catalysts

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