Chinese Journal of Applied Chemistry ›› 1995, Vol. 0 ›› Issue (4): 93-95.
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Yue Guoren, Wang Jianhua, Zhang Zheng
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Abstract: When Mckillop's method was used,oxidation of cyano-containing organic sulfidesto the corresponding stilfones with sodium perborate tetrahydrate(NaBO3· 4H2O)causedthe hydrolysis of cyano group.However,with our modified procedure in which the reagentsodium perborate was added in small portions at 55~65℃,sulfones and sulfoxides could beselectively obtained and the cyano group was not touched.
Key words: cyano-containing sulfide, selective oxidation, sodium perborate tetrahydrate
Yue Guoren, Wang Jianhua, Zhang Zheng. Selective Oxidation of Cyano-containing P-Nitrophenyl Sulfides[J]. Chinese Journal of Applied Chemistry, 1995, 0(4): 93-95.
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