Studies on Solid State Reactions of Coordination Compounds LXⅧ. The Solid State Reaction of 2-Aminopyrimidine with Copper(Ⅱ) Compounds at Room Temperature

Chinese Journal of Applied Chemistry ›› 1994, Vol. 0 ›› Issue (6): 7-11.

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Studies on Solid State Reactions of Coordination Compounds LXⅧ. The Solid State Reaction of 2-Aminopyrimidine with Copper(Ⅱ) Compounds at Room Temperature

Yao Xuebin¹, Zheng Limin¹, Xin Xinquan¹, Jin Tongzheng²

1. State key Laboratory of Coordination Chemistry, Department of Chemistry, Nanjing University, Nanjing 210008;
2. Center of Modern Analysis, Nanjing University, Nanjing

Received:1994-02-21 Revised:1994-05-16 Published:1994-12-10 Online:1994-12-10

Abstract

Abstract: The solid state reactions of 2-aminopyrimidine(AP)with CuCl₂·2H₂O,CuBr₂,CuSO₄·5H₂O and CuAc₂·H₂O at room or near room temperature result in the formation of three kinds of complexes with coordination ratio Cu/AP=1:2,1:1 and 2:1 respectively. The solid products were chracterized by elemental analysis,XRD,ICP, UV, ESR methods. The mechanism of this kind of reations and the effects of copper and the reagents were discussed.

Key words: solid state reaction, aminopyrimidine, copper(Ⅱ)complex

Yao Xuebin, Zheng Limin, Xin Xinquan, Jin Tongzheng. Studies on Solid State Reactions of Coordination Compounds LXⅧ. The Solid State Reaction of 2-Aminopyrimidine with Copper(Ⅱ) Compounds at Room Temperature[J]. Chinese Journal of Applied Chemistry, 1994, 0(6): 7-11.

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Studies on Solid State Reactions of Coordination Compounds LXⅧ. The Solid State Reaction of 2-Aminopyrimidine with Copper(Ⅱ) Compounds at Room Temperature

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