Chinese Journal of Applied Chemistry ›› 1994, Vol. 0 ›› Issue (5): 104-106.

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Products of Cyclisation and Mannich Condensation of Methylenedinitramine

Wei Yunyang, Lu Chunxu, Lu Ming, Wang Yu, Li Zhiping   

  1. Institute of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210014
  • Received:1993-11-03 Revised:1994-05-03 Published:1994-10-10 Online:1994-10-10

Abstract: Methylenedinitramine(1) was synthesized via a new route,N-alkylation of 1 gave a new polynitropolyazatricyclonitramine(2). An improved method for the synthesis of 3,7-dinitro-1,3,5,7-tetraazabicyclo[3.3.1]nonane(3,DPT) from 1 was proposed.

Key words: high energy density material, methylenedinitramine, N-alkylation, cyclization, Mannich condensation