MASS SPECTROMETRIC STUDY ON ORGANICPHORSPHORUS COMPOUNDS Ⅹ.EI MASS SPECTROMETRIC STUDY ON 1,2-DIPHENYL-3,3-DIALKYL-1,4,2-DIAZAPHOSPHOLIDIN-5-ONE-2-OXIDE

Chinese Journal of Applied Chemistry ›› 1993, Vol. 0 ›› Issue (1): 34-38.

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MASS SPECTROMETRIC STUDY ON ORGANICPHORSPHORUS COMPOUNDS Ⅹ.EI MASS SPECTROMETRIC STUDY ON 1,2-DIPHENYL-3,3-DIALKYL-1,4,2-DIAZAPHOSPHOLIDIN-5-ONE-2-OXIDE

Qiu Fenghe¹, Song Fengrui¹, Liu Shuying¹, Feng Kesheng², Chen Ruyu²

1. Changchun Institute of Applied Chemistry, Academia Sinica, 130022 Changchun;
2. Institute of Elemento-Organic Chemistry, Nankai University, Tian jin

Received:1991-06-14 Revised:1991-09-24 Published:1993-02-10 Online:1993-02-10

Abstract

Abstract: The EI mass spectra of 13 phorsphorus-containing compounds were reported. The EI spectra of these compounds are characterized by cycle opening cleavage and rearrangement under electron impact conditions. Some rearrangement processes were reported in detail. The substituent effects on fragmentation mechanism of molecular ions were also discussed.

Key words: phorsphoros-containing compound, hetero-cyclic compound, fragmentation mechanism, electron ionization mass spectrometry

Qiu Fenghe, Song Fengrui, Liu Shuying, Feng Kesheng, Chen Ruyu. MASS SPECTROMETRIC STUDY ON ORGANICPHORSPHORUS COMPOUNDS Ⅹ.EI MASS SPECTROMETRIC STUDY ON 1,2-DIPHENYL-3,3-DIALKYL-1,4,2-DIAZAPHOSPHOLIDIN-5-ONE-2-OXIDE[J]. Chinese Journal of Applied Chemistry, 1993, 0(1): 34-38.

MASS SPECTROMETRIC STUDY ON ORGANICPHORSPHORUS COMPOUNDS Ⅹ.EI MASS SPECTROMETRIC STUDY ON 1,2-DIPHENYL-3,3-DIALKYL-1,4,2-DIAZAPHOSPHOLIDIN-5-ONE-2-OXIDE

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