Chinese Journal of Applied Chemistry ›› 1992, Vol. 0 ›› Issue (3): 110-113.

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SYNTHESIS AND CHARACTERIZATION OF CYCLOPENTADIENYL (OR METHYLCYCLOPENTADIENYL)TITANIUM (Ⅳ) ZIRCONIUM(Ⅳ) TRISDITHIOCARBAMATES

Lü Zhengrong1, Gao Songqi2, Zhou Yaokun3, Wu Shaozu3   

  1. 1. Deparment of Chemistry, Department of Environmental Science, Wuhan University, Wuhan 430072;
    2. Department of Chemistry, Lanzhou University, Lanzhou
  • Received:1991-06-25 Revised:1991-12-18 Published:1992-06-10 Online:1992-06-10

Abstract: Thirteen new compounds of type (RCp)M(S2CNR2)3 were synthesized by reacting (RCp)2MCl2(R=H, Me;M=Ti(Ⅳ), Zr(Ⅳ)) with sodium pyrrolidine-, piperidine- and morpholine-dithiocarbamates, respectively. The IR spectra showed that the dithiocarhamic ligands behave as bidentate ligands in the complexes. The 1H-NMR spectra showed that all complexes are rigid compounds.

Key words: cyelopentadienyl, titanium, zirconium, dithiocarbamate