Chinese Journal of Applied Chemistry ›› 1991, Vol. 0 ›› Issue (4): 96-100.

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SYNTHESIS OF N-ALKYL DERIVATIVES OF 7-OXA-BICYCLO[2.2.1]-HEPT-5-ENE-2,3-DICARBOXIMIDE THROUGH PHASE TRANSFER CATALYSIS

Zhong Qi, Ge Xinying, Shao Jiangguo   

  1. Department of Chemistry, Yangzhou Teachers College, Yangzhou 225002
  • Received:1990-08-21 Revised:1990-12-24 Published:1991-08-10 Online:1991-08-10

Abstract: Eleven N-alkyl derivatives of 7-oxabicyclo [2.2.1]-hept-5-ene-2, 3-dicarboximide havebeen synthesized in yields of 71~96.7% using PEG-400 as phase transfer catalyst.N-Al-kylation is a pseudo first order in respect to the concentration of dicarboximide.

Key words: oxabicyclo [2.2.1]-heptene-dicarboximide, N-alkylation, phase transfer catalysis