SATURATED URUSHIOL CROWN THALLIUM(Ⅰ)ION-SELECTIVE ELECTRODES:CROWN ETHER STRUCTURE AND PROPERTIES OF ELECTRODES

Chinese Journal of Applied Chemistry ›› 1991, Vol. 0 ›› Issue (4): 25-29.

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SATURATED URUSHIOL CROWN THALLIUM(Ⅰ)ION-SELECTIVE ELECTRODES:CROWN ETHER STRUCTURE AND PROPERTIES OF ELECTRODES

Huang Zaifu, Wan Huijie, Hu Weidong, Yang Songhui, Lai Zhiqiang

Department of Environmental Science, Wuhan University, Wuhan 430072

Received:1990-08-01 Revised:1990-11-27 Published:1991-08-10 Online:1991-08-10

Abstract

Abstract: Ten thallium(I) ion PVC membrane electrodes based on eight saturated urushiol crownethers were prepared.Electrodes of no.1 and 4 appeared the best ones their comprehensiveproperties.They exhibited linear responses in 4×10^-7～5×10^-1 and 8×10^-7～1×10^-1mol/L TlNO₃, respectively.The electrodes showed a higher selectivity to K ion than othercrown ether Tl(I) electrodes reported in the literature.

Key words: urushiol, crown ether, thallium, ion selective electrode

Huang Zaifu, Wan Huijie, Hu Weidong, Yang Songhui, Lai Zhiqiang. SATURATED URUSHIOL CROWN THALLIUM(Ⅰ)ION-SELECTIVE ELECTRODES:CROWN ETHER STRUCTURE AND PROPERTIES OF ELECTRODES[J]. Chinese Journal of Applied Chemistry, 1991, 0(4): 25-29.

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SATURATED URUSHIOL CROWN THALLIUM(Ⅰ)ION-SELECTIVE ELECTRODES:CROWN ETHER STRUCTURE AND PROPERTIES OF ELECTRODES

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